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Dipole moments of the carbonyl groups in cyclic β-diketones from IR spectroscopy data (1995)

Pisarenko, L. M. ; Nikitin, A. V.

Springer

Russian chemical bulletin 44 (1995), S. 670-677

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Details

ISSN: 1573-9171

Schlagwort(e): IR spectroscopy ; dipole moments ; coplanar arrangement ; carbonyl groups ; 2-arylindan-1,3-diones

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie

Notizen: Abstract The αCO angles between the carbonyl groups and the dipole moments of a number of 2-arylindan-1,3-diones were determined from the data of IR spectroscopy. The effects of substituents on αCO depending on their positions and inductive factors were found. It was established that the interaction between the vibrations of the carbonyl groups depends on both the αCO angle or the ΣμCO dipole moment and the coplanar arrangement of these groups.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF00698501

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