ISSN:
0009-2940
Keywords:
1,2-Dihydro-1,3,2λ5,4λ5-diazadiphosphete
;
Isomerization
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
1,2-Dihydro-1,3,2λ5,4λ5-diazadiphosphete - Synthesis, Structure and Isomerization to the „Inner Salt“ of 1,3,2,4λ5-Diazadiphosphetan-2-ium HydroxideThe photochemical reaction of the azidophosphane (iPr2N)2PN3 (1) with the tetraazaphospholene (3) and the bis(imino)phosphorane (Me3Si)2NP(=NSiMe3)2 (6) proceeds by elimination of N2 to yield (5) and by 1,3-silyl group shift to furnish (8) the structures of which were determined by means of NMR data and, in the case of 5, additionally by X-ray structure analysis.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19921251202
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