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  • 1
    Electronic Resource
    Electronic Resource
    Kinetics and mechanism of diethanolamine degradation in aqueous solutions containing carbon dioxide (1984)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 16 (1984), S. 1257-1266 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The problem of diethanolamine (DEA) degradation in gas-treating processes was quantified through a detailed kinetic study. This reaction was found to be catalyzed by CO2, and degradation occurs in a successive manner to 3-(2-hydroxyethyl)oxazolidone-2, to N,N,N′-tris(2-hydroxyethyl)ethylenediamine and then to N,N′-bis(2-hydroxyethyl)piperazine. A reaction mechanism consistent with these observations was proposed and tested through kinetic analyses. A satisfactory kinetic model which can be of practical use was derived.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550161008
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