ISSN:
0449-2978
Schlagwort(e):
Physics
;
Polymer and Materials Science
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
,
Physik
Notizen:
Light scattering and viscosity have been measured at 25°C. for dilute solutions of six unfractionated polyoxymethylene samples in the mixed solvent hexafluoroacetone-water (mole ratio 1/1.7) slightly buffered with triethylamine. Dialysis equilibrium through porous Vycor glass thimbles indicates that the polymer is strongly solvated by the hydrate (CF3)2C(OH)2, and this must be taken into account in evaluating weight-average molecular weights from the light-scattering data. Over the molecular weight range 23,000-185,000, the intrinsic viscosities (in deciliter per gram) follow the relation \documentclass{article}\pagestyle{empty}\begin{document}$ [\eta] = 8.7{\rm} \times {\rm}10^{ - 4} M_\upsilon ^{0.69} $\end{document} The corresponding unperturbed dimensions are σ = 2.3 ± 0.2 or r02/nl2 = 10.5 ± 1.5.
Zusätzliches Material:
3 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/pol.1966.160040313
Permalink
