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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Langmuir 11 (1995), S. 3337-3346 
    ISSN: 1520-5827
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Macromolecules 24 (1991), S. 2890-2895 
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 509 (Mar. 2006), p. 177-186 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 62 (1991), S. 1255-1266 
    ISSN: 1572-9613
    Keywords: Dilute polymer solutions ; dumbbell model ; hydrodynamic interactions ; rheological properties ; elongational flows
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Dumbbell models are only crude representations of actual polymer molecules, but their simplicity allows for explicit calculations which in many instances have shed light on the connection between molecular properties and rheological behavior. On the other hand, hydrodynamic interactions are known to strongly influence the dynamic response of polymer solutions and this makes the representation of the hydrodynamic drag an important aspect in the calculations. In the present work, the effects of the state of flow are incorporated explicitly in the frictional properties of the FENE model of a dilute polymer solution. Results for the steady elongational viscosity and the mean square end-to-end distance arc presented.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 277 (1999), S. 743-751 
    ISSN: 1435-1536
    Keywords: Key words Nonlinear dumbbell model ; Polyelectrolyte solutions ; Narrow channels ; Flow birefringence ; Slip velocity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The shear flow of dilute polyelectrolyte solutions bounded by either neutral or repulsive walls is modeled using a nonlinear dumbbell with conformation-dependent friction. Assuming that the configurational probability density function depends on the internal coordinates (r) and the distance of the center of mass of the molecule to the walls, coupled differential equations for the tensor moments 〈rr〉 are obtained. Coulombic repulsion between beads is considered to simulate the charge repulsion between ionized sites distributed along the backbone of a real polyelectrolyte. The repulsive interaction between the polyelectrolyte molecule and the charged walls is that of the DLVO model and the molecule is considered to be a charged sphere. Numerical solutions for the components of the tensor 〈rr〉 are worked out with the preaverage approach, and only when neutral walls considered are exact solutions obtained. Viscosity results show that in the limit of very wide channels, the corresponding viscosity in the bulk is obtained. The wall repulsion on the charged molecules produces migration of molecules towards the center of the channel resulting in a depleted layer with lower viscosity next to the walls. The calculated slip phenomenon using the method employed by Grisafi and Brunn is dependent on the beads repulsion and the shear rate. The slip velocity obtained with the Mooney method shows similarities with available experimental results for polyelectrolyte solutions. Birefringence calculations are performed in narrow and wide channels for different bead repulsions, with interesting results for both flexible and rigid molecules.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1435-1536
    Keywords: Key words Relaxation spectrum ; linear viscoelasticity ; surfactants ; dispersions ; worm-like micelles
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract  In this work, the linear viscoelastic properties of cetyl-trimethylammonium tosilate–water system are predicted by the modeling of the relaxation spectrum. The modeled spectrum of relaxation times is of the “wedge-box” type where the “wedge” portion is located at the short-time scale of relaxation times and the “box” part covers the long-time scale. The linear viscoelastic properties are calculated through the exact relationships with the suggested spectrum. Agreement between the calculated expressions and experimental data of the moduli and the stress relaxation function is found. Comparison is also made with predictions of the empirical expressions of the Cole–Cole and the Williams–Watts models.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 26 (1991), S. 565-570 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Polysulfobetaine polymers present highly polar lateral groups with zwitterionic structures and such molecular characteristics are highly desirable in the production of ionic conductive systems. The extent of their conductive properties is significantly dependent on the morphological changes which take place in their mixtures with salts when temperature is varied. As soon as the salt melts and dissolves in the polymer matrix, conductivity increases sharply for unusually high salt proportions, attaining a level similar to that observed in the pure polymer. Microscopic observations of these systems reveal interesting morphological changes associated with the onset of high conductivity.
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary We have conducted observations of possible microstructure on some zwitterionic polymers by means of Transmission Electron Microscopy. Two different solvents, with very different evaporation rates, were used to dessicate the samples onto the carbon covered microscope grids. While no sign of microstructure was apparent in the samples prepared from the more volatile solvent, a well defined grainy appearance was observed in the samples obtained from the less volatile solvent. This shows that sample preparation plays an important role on microstructure formation on zwitterionic polymers.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Rheologica acta 27 (1988), S. 217-223 
    ISSN: 1435-1528
    Keywords: Irreversiblethermodynamics ; non-linearviscoelasticity ; Oldroyd model ; constitutive equation ; structural theory ; rheological equation of state
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Abstract We show that Extended Irreversible Thermodynamics (EIT) may be regarded as a unifying thermodynamic scheme which generates a variety of non-linear viscoelastic equations of state. In particular, we show how the so-called eight-constants Oldroyd model, with all its invariant properties, may be derived from the postulates of EIT. It is also shown that the structure of the thermodynamic based rheological equations of state is in complete agreement with that of the representation theorems formulation of constitutive relationships originally proposed by Rivlin and Ericksen. We discuss how more complex rheological models can be derived from higher order approximations of the theory. Finally, the connections between our approach and other related works are briefly discussed.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Rheologica acta 19 (1980), S. 277-284 
    ISSN: 1435-1528
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Zusammenfassung Es werden zwei Typen instationärer Rohrströmungen theoretisch betrachtet. Bei dem ersten wird eine kombinierte stationäre und oszillierende Scherströmung dadurch erzeugt, daß bei ruhendem Rohr der Strömung ein pulsierender Druckgradient aufgeprägt wird. Bei dem zweiten ist der Druckgradient konstant, dagegen führt das Rohr axiale Schwingungen aus. Die theoretische Analyse wird für das Modell einer verallgemeinerten Maxwell-Oldroyd-FlüssigkeitB (d. h. mit kontravarianter konvektiver Zeitableitung) durchgeführt, welches durch eine Viskositätsfunktion, aber nur eine einzige Relaxationszeit gekennzeichnet ist. Es wird gezeigt, daß die üblichen Störungsmethoden nicht geeignet sind, einige der interessantesten experimentellen Beobachtungen zu beschreiben. Daher wird in den meisten Fällen eine auf den Arbeiten vonTownsend basierenden Finite-Differenzen-Methode angewendet. Bei der Analyse des vibrierenden Rohrs wird geschlossen, daß die Strömung maßgeblich durch die Axialbewegung des Rohrs bestimmt sein muß, wenn die interessanten Experimente vonManero undMena angemessen interpretiert werden sollen. Zur Zeit ist noch nicht eine solche Stufe des theoretischen Verständnisses erreicht, von wo aus einequantitative Voraussage der bekannten experimentellen Ergebnisse bei pulsierenden Strömungen bzw. einem vibrierenden Rohr geleistet werden könnte.
    Notes: Summary Theoretical consideration is given to two unsteady pipe flows. In the first, a combined steady and oscillatory shear flow is generated by a pulsatile pressure gradient in a stationary pipe. In the second, the pressure gradient is constant, but the pipe wall executes axial vibrations. The theoretical analysis is carried out for an upper convected Maxwell model characterized by a viscosity function and one relaxation time. A conventional perturbation method of solution is concluded to be inadequate to describe some of the interesting experimental observations and most of the work employs a finite-difference formulation based onTownsend's work. In the vibrating-pipe analysis, it is concluded that the flow must be considered to be dominated by the axial movement of the pipe if the interesting experiments ofManero andMena are to be properly interpreted. We have still not reached the stage where existing experimental results on pulsatile flow and the vibratingpipe situation can bequantitatively predicted.
    Type of Medium: Electronic Resource
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