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  • 1
    Electronic Resource
    Electronic Resource
    Diastereoselektive Synthese von (1RS)-endo-Brevicomin (1984)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1984 (1984), S. 147-156 
    Details
    ISSN: 0170-2041
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Diastereoselective Synthesis of (1RS)-endo-Brevicomin(1RS-endo-Brevicomin (1) is synthesized starting from trans-1-bromo-2-pentene. Synthetic key step is the diastereoselective linkage of erythro-2,3-butanediol to 3,3-dimethoxy-1-(phenylsulfonyl)-butane or methyl 4,4-dimethoxypentanoate.
    Notes: (1RS)-endo-Brevicomin (1) wird ausgehend von trans-1-Brom-2-penten synthetisiert. Schlüsselreaktion ist die diastereoselektive Verknüpfung von erythro-2,3-Butandiol mit 3,3-Dimethoxy-1-(phenylsulfonyl)butan oder 4,4-Dimethoxypentansäure-methylester.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jlac.198419840115
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Synthese von (1S)-(-)-Frontalin (1983)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1983 (1983), S. 913-921 
    Details
    ISSN: 0170-2041
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Synthesis of (1S)-(-)-FrontalinThe aggregation pheromone 1 of the southern pine beetle Dendroctonus frontalis has been synthesized in high optical yield starting from (2R)-2-methyl-2-epoxy-1-propanol (4) which is obtained from methallyl alcohol (3) via enantioselective epoxidation according according to Sharpless9).
    Notes: Das Aggretationspheromon 1 des Borkenkäfers Dendroctonus frontalis wird in hoher optischer Reinheit ausgehend von (2R)-2-Methyl-2-epoxy-1-propanol (4) synthetisiert. 4 wird durch enantioselektive Epoxidierung von Methallylalkohol (3) analog der von Sharpless9) beschriebenen Methode erhalten.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jlac.198319830604
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    Paper (German National Licenses)
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