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  • 1
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Ferrous trimethylammonium chloride (FeTAC) is a member of a family of compounds that consist of chains of bihalide-bridged metal ions aligned along the b axis of the orthorhombic unit cell. The chains are connected in (bc) planes by hydrogen bonding of the waters of hydration; these planes are isolated along the a axis by the large trimethylammonium groups. FeTAC orders three dimensionally below TN=3.16 K, with the moments, which are canted from the b axis by ∼20°, coupled ferromagnetically along the b axis and staggered along the [101] direction. The order parameter follows the exact Onsager solution for a rectangular 2D Ising lattice below T/TN≈0.95, with ratio for the two in-plane magnetic exchange constants of 1.3×10−3. However, quasielastic scattering measurements in the vicinity of TN show that the correlations do not evolve as do those of the 2D Ising antiferromagnets ErBa2Cu3O7 and K2CoF4. Above TN, magnetic excitations along the b axis that follow the dispersion relation of a 1D ferromagnet with a gap of 3.7 meV have been observed.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 67 (1990), S. 5604-5606 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Previous magnetic measurements on FeTAC, [(CH3)3NH]FeCl3⋅2H2O, have shown it to behave as a one-dimensional Ising ferromagnet with an exchange constant J/k=17.4 K. A transition to an ordered state was observed near 3.1 K. Whether the transition was to a state of two- (2D) or three-dimensional long-range order could not be determined from the magnetic study. The specific-heat measurements reported here confirm the value of the intrachain exchange constant and show the critical temperature to be 3.135 K. Lattice dimensionality crossover is observed. The data are well described by Onsager's rectangular 2D Ising lattice, with a ratio of exchange constants ||J'/J||=1.3×10−3. The high degree of one-dimensional isolation found for FeTAC makes it an attractive candidate for studies of linear-chain magnetism.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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