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  • 1
    Electronic Resource
    Electronic Resource
    Conjugate addition of water to α-carbonylcarbenes (1998)
    Chichester : Wiley-Blackwell
    Journal of Physical Organic Chemistry 11 (1998), S. 610-613 
    Details
    ISSN: 0894-3230
    Keywords: Conjugate addition ; α-carbonylcarbenes ; water ; Chemistry ; Theoretical, Physical and Computational Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: α-Carbonylcarbenes (2a-c) generated by UV photolysis of 2-diazophenylacetic acid (1a), its methyl ester (1b) and 4-diazo-3-isochromanone (1c) in aqueous solution undergo conjugate addition of water across the entire carbonylcarbene moiety to give enols (3a-c) of the corresponding α-hydroxycarbonyl compounds. These carbenes are long-lived, with microsecond lifetimes in aqueous solution. © 1998 John Wiley & Sons, Ltd.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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