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Digitale Medien

Chemical reactivity of CO and CO2 at a Cu(110)-Cs surface (1994)

Carley, A. F. ; Roberts, M. W. ; Strutt, A. J.

Springer

Catalysis letters 29 (1994), S. 169-175

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Details

ISSN: 1572-879X

Schlagwort(e): carbon dioxide ; carbon monoxide ; cesium ; copper ; electron spectroscopy

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie

Notizen: Abstract Carbon dioxide and carbon monoxide undergo reactive chemisorption with cesium modified Cu(110) and Cu(110)-O surfaces and via the anionic intermediate CO 2 δ− (a) form a surface carbonate. The CO 2 δ− (a) species was characterised by VEELS and XPS at low temperature (80 K) and the surface carbonate at 295 K. For cesium modified Cu(110) surfaces chemisorption of carbon monoxide gives rise to electron energy loss peaks (v co) as low as 1450 cm−1 at 295 K.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF00814263

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