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Digitale Medien

Rhodium supported in basic zeolite Y: A selective and stable catalyst for CO hydrogenation (1991)

Lee, T. J. ; Gates, B. C.

Springer

Catalysis letters 8 (1991), S. 15-21

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Details

ISSN: 1572-879X

Schlagwort(e): CO hydrogenation ; zeolite Y ; rhodium carbonyl clusters ; catalyst selectivity ; catalyst stabilization

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie

Notizen: Abstract Catalysts prepared by a condensation reaction of Rh(CO)2(acac) within the supercages of zeolite Y made basic by treatment with NaN3 are active for CO hydrogenation and selective for low-molecular-weight olefins and methanol. High partial pressures of CO (or CO + H2) stabilize the catalyst. The predominant species in the catalyst are suggested to be rhodium carbonyl clusters trapped in the zeolite cages.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF00764378

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