Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
91 (1989), S. 1232-1241
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
Analytical solution to the restricted-diffusion-in-a-cone model for a symmetric top is obtained using a set of orthogonal functions of nonintegral order. It is shown that the case of the restricted-diffusion-in-a-cone model for an asymmetric top cannot be solved in analytical closed form: Series solution is, however, possible. The correlation functions for arbitrary functions of the orientation of a rigid body are also obtained. These functions are required in obtaining the correlation functions for the restricted rotational diffusion of articulated bodies and are useful in interpreting the data from relaxation experiments for determining the diffusion coefficients and conal restriction angles.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.457197
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