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  • 1
    Digitale Medien
    Digitale Medien
    s.l. : American Chemical Society
    The @journal of organic chemistry 30 (1965), S. 3328-3332 
    ISSN: 1520-6904
    Quelle: ACS Legacy Archives
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 99 (1993), S. 8430-8439 
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: The zero-kinetic-energy (ZEKE) photoelectron spectrum of carbon dioxide has been measured between 111 000 and 112 000 cm−1 at a resolution of 1.5 cm−1 using a coherent source of XUV radiation based on four-wave mixing in krypton. The spectrum consists of six bands corresponding to transitions from the ground X 1Σ+g(v1,v2,v3=000) state of the neutral to the two spin–orbit components of the (000) vibrational level and the four Renner–Teller states associated with the (010) vibrational level of the ground electronic state (X 2Πg) of the ion. The analysis of the partially resolved rotational structure of the various bands leads to a detailed picture of the photoionization process. The propensity rules for angular momentum transfer during photoionization are strongly dependent on the symmetry (2Πg,3/2, 2Πg,1/2, 2Δu,5/2, 2Δu,3/2, 2Σ+u, and 2Σ−u) of the different ionic states probed and on the Hund's coupling case they follow [case (a) for the Π and Δ states and case (b) for the Σ states]. A comparison of the experimental ZEKE line intensities with theoretical predictions and conventional photoelectron spectra reveals a series of anomalies which are discussed in terms of final state interactions. The ionization potential of CO2 is estimated to be 111 111.0±3 cm−1, somewhat lower than the value of 111 121±2 cm−1 determined from extrapolation of the Rydberg series by Cossart-Magos et al. [Mol. Phys. 61, 1077 (1987)].
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 62 (1991), S. 1326-1332 
    ISSN: 1089-7623
    Quelle: AIP Digital Archive
    Thema: Physik , Elektrotechnik, Elektronik, Nachrichtentechnik
    Notizen: The Kelvin probe, used to measure changes in work function (wf), has proved particularly useful as a UHV surface analysis technique, having applications in the study of thin films, adsorption kinetics, surface photovoltage spectroscopy, surface topographies, etc. However the Kelvin circuit is plagued by noise problems, which are considerably enhanced by long connecting wires and the nonideal UHV environment. Careful shielding is essential in order to improve the signal-to-noise (S/N) ratio, especially at backing potentials close to the null condition. Although lock-in-amplifier (LIA) based automatic compensation systems are available they operate on low signal levels and are prone to electromagnetic pickup from the driving element and mechanical instabilities of the vibrating capacitor. We discuss the general noise spectrum and describe an alternative "off-null'' approach utilizing a data-acquisition-system (DAS) based measuring system that features an active suspension system (ASS), automatic set-up, and software elimination of driver talkover. This system has applications where very high resolution (〈0.1 meV) is required, or if low S/N ratios caused by reduced probe dimensions or a high noise background would otherwise prejudice the measurement.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 99 (1993), S. 4213-4214 
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: A novel method of preparing ions in selected rovibronic states is presented. It is based on pulsed field ionization of long-lived high-n Rydberg states lying just below the different rovibronic energy levels of the ion. The potential of the method is illustrated with the example of hydrogen: A clean population of H2+ ions is prepared in the X 2∑g+ (v+=2, N+=0, 1, 2, 3) states. The method ought to be applicable to the preparation of a wide range of small molecular ions in selected rotational states and opens new possibilities in the study of state-to-state ion–molecule reactions.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    s.l. : American Chemical Society
    The @journal of organic chemistry 35 (1970), S. 2673-2677 
    ISSN: 1520-6904
    Quelle: ACS Legacy Archives
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    s.l. : American Chemical Society
    The @journal of organic chemistry 37 (1972), S. 1579-1583 
    ISSN: 1520-6904
    Quelle: ACS Legacy Archives
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 101 (1994), S. 10609-10617 
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: A new apparatus is described in which a beam of molecular ions in a selected vibration–rotation state is prepared by field ionization of high Rydberg states, in an adaptation of the zero-kinetic-energy photoelectron technique. The state-selected ions undergo low energy reactive collisions within a molecular beam and the ionic products are detected in a quadrupole mass filter. The Rydberg states are populated by two-color stepwise multiphoton excitation, and by tuning to the pseudocontinuum of high-Rydberg states associated with different vibration–rotation states of the ion core, different states of the ion are selected and the effect on reactivity determined. Some preliminary results for the H2+H+2→H+3+H reaction are reported. © 1994 American Institute of Physics.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 8
    Digitale Medien
    Digitale Medien
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 103 (1995), S. 4509-4518 
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: The decay dynamics of the high Rydberg states of N2 converging on the first few rotational levels (N+=0,1,2,3) of the ground vibronic X 2Σ+g (v+=0) state of the N+2 cation have been investigated by delayed pulsed field ionization (PFI) following two-photon enhanced (2+1′) three-photon excitation via the a″ 1Σ+g (v′=0) state of N2. The experiments were carried out in the presence of a weak homogeneous dc electric field and at typical ion densities of 200–2000 ions/mm3. All Rydberg states in the range of principal quantum number n=140–200 exhibit extreme stability against autoionization and predissociation and some have lifetimes which exceed 30 μs. The decay of the highest Rydberg states beyond n=200 is induced by external perturbations (field ionization and collisional ionization) and no Rydberg states beyond n=350 can be observed by delayed PFI. The Rydberg states which converge on the N+=0 and 1 rotational levels of the ion, and which therefore are not subject to rotational autoionization, decay into neutral products (by a process presumed to be predissociation) in less than 7 μs in the range n〈100. The importance of predissociation is greatly reduced beyond n=100 and becomes negligible on our experimental timescale (30 μs) above n=140. The decay of the Rydberg states converging on the N+=2 and 3 rotational levels of the ion is more complex. Below n=100, only 30%–40% of the Rydberg population decays by fast rotational autoionization whereas 60%–70% decays by predissociation.The importance of predissociation decreases rapidly above n=100 and becomes negligible beyond n=140. The decay by rotational autoionization can be observed at all n values but becomes noticeably slower beyond n=100. In the range n=140–200 it exhibits a marked biexponential decaying behavior with 30% of the population decaying within a few microseconds and 70% displaying long term stability (τ(approximately-greater-than)30 μs). The branching between predissociation and autoionization is explained by the effect of the dc electric field which mixes strongly the optically accessible p Rydberg series with the high l manifold beyond n=100. The long lifetimes observed experimentally indicate that ml mixing becomes important as soon as l mixing sets in. © 1995 American Institute of Physics.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    s.l. : American Chemical Society
    The @journal of organic chemistry 28 (1963), S. 717-720 
    ISSN: 1520-6904
    Quelle: ACS Legacy Archives
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 10
    Digitale Medien
    Digitale Medien
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 105 (1996), S. 11360-11363 
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: We describe a novel mechanism for efficient generation of open shell free-radical complexes via UV photolysis of the corresponding closed shell precursors. Ar–SH and Ar2–SH are detected following 248 nm excitation of Ar–H2S and Ar2–H2S. Of particular dynamical interest are the nonfragmentary channels in which no Ar atoms are ejected. © 1996 American Institute of Physics.
    Materialart: Digitale Medien
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