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  • 1
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary A new alcoholate of cyclopentadienyl metallocene with voluminous group as ligand substituting chlorine atoms and formula Cp2Hf(OMAd)2 (where Cp = cyclopentadienyl and OMAd = derived of 2-methyl-2-adamantol) was synthesized and employed as catalyst for olefin polymerization. The compound was evaluated in ethylene polymerization activated by methylaluminoxane (MAO) using several experimental conditions. These conditions were determined by a statistic method, and a model for dependent variables like catalyst activity and average molecular weight of polymers were developed. The hafnocene alcoholate produced polyethylenes with molecular weights in the same range of the corresponding metallocene dichloride. The new catalyst system showed high stability under temperature of 100°C. In the presence of H2 as molecular weight controlling agent, the catalyst showed a maximum of activity in the concentration range used.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 230-232 (Oct. 2002), p. 152-156 
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 230-232 (Oct. 2002), p. 255-258 
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 514-516 (May 2006), p. 564-568 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The quality of a mechanical component such as its geometrical accuracy stability andfatigue life are significantly affected by the surface integrity generated by machining process. Residual stresses are a major part of the mechanical state of a machined layer and they can be beneficial or detrimental depending of their nature and magnitude. This study concerns phase analysis and residual stress profile characterization by X-ray diffraction (XRD) technique and microhardness profile of AISI H13 ESR mould steel, milled using carbide and CBN tools.Analysis of the cross-section of the AISI H13 ESR samples, milled using both tools, reveal a martensitic microstructure, with a very thin layer heavily deformed due to the machining process. However, no phase transformation was detected by XRD.Concerning the residual stresses, the results show that they are predominantly compressive at the samples surface. However, depending of the cutting tools, the in-depth residual stresses profiles present different evolutions. This difference in the in-depth residual stresses profiles between the two kind of cutting tools is attributed to the different cutting tool parameters, including the tool geometry
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 514-516 (May 2006), p. 1613-1617 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The thin and textured coatings present a double difficulty for characterization byconventional X-ray diffraction. Their shallow depth reduces the diffracted intensity and allows theinterference of the underlying material. Frequently they present a crystallographic texture whichlimits the number of orientations that provide good intensity and induces anisotropy effects on theirmechanical behavior. Reliable results can be determined using diffraction geometry of lowincidenceangle. This paper describes the application of the technique to several films, characterizedby thicknesses of the order of 1 μm and crystallographic textures. Examples are proposed ofchromium films applied by PVD on molybdenum substrates, decorative electroplated coatings, andaluminum coatings used for interconnections in microelectronic circuits. The Cr films are 1.5 μmthick and exhibit a strong 〈100〉 fiber texture. The decorative coatings were studied both on thenickel undercoat and in the Cr top layer. Results are presented for chromium where tensile stressesand a 〈110〉 fiber texture were observed. The Al films are 1.0 μm thick. Some samples were heattreatedat different annealing temperatures. Tensile stresses were always observed, which increase inthe annealed samples
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 514-516 (May 2006), p. 1618-1622 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The conventional Bragg diffraction geometry, normally used to characterize the residualsurface stress state, it is not suitable to evaluate surface treated materials and thin films. The X-raypath lengths through a surface layer or thin film are too short to produce adequate diffractionintensities in relation to the bulk or the substrate. Another limitation of the conventional techniqueappears when a residual stress gradient is present in the irradiated surface. The technique onlyenables the evaluation of the mean value of this gradient. In these cases, a recently proposedPseudo-Grazing Incident X-ray Diffraction method would be better applicable.In this study, the Pseudo-Grazing Incidence X-ray Diffraction is applied to characterize the residualstress depth profiles of several AISI 4140 samples, which were prepared, by mechanical polishingand grinding, in order to present different surface roughness parameters, Ra. The experimentalresults lead to the conclusion that the surface roughness limits the application of thePseudo-Grazing Incidence methodology to a minimum X-ray incident angle. This angle is the onethat enables a mean X-ray penetration depth with the same order of magnitude of the sample surfaceroughness parameter, Ra
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 30 (1993), S. 377-383 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Copolymerizations of ethylene or propylene with butadiene, 1,5-hexadiene or 1,7-octadiene by MgH2/TiCl4-AlEt3 catalyst system were carried out. The effect of diene concentration in the reaction medium for each polymerization system on catalytic activity was observed. The compositions of the obtained copolymers were evaluated and the reactivity ratios were determined. Ethylene-propylene-diene terpolymerizations with the same catalyst system were also investigated.
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract. Y zeolites with different aluminium contents obtained by dealumination with ammonium hexafluorosilicate were evaluated as supports for bis(cyclopentadienyl)zirconium dichloride catalysts. The activities of the supported and homogeneous systems were compared for ethylene polymerization. The most active heterogeneous catalyst was the one supported on the zeolite with the higher Si/Al ratio and external area.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 31 (1993), S. 219-225 
    ISSN: 0887-624X
    Keywords: polymerization ; molecular weight ; ethylene ; Ziegler-Natta ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: This article describes studies on the variables that regulate the molecular weight in ethylene polymerization using a highly active Ziegler-Natta catalyst with hydrogen for molecular weight control. The dependence of the degree of polymerization on the concentration of catalyst, cocatalyst, monomer, partial pressure of hydrogen, and temperature has been established. The rate constant for chain transfer with cocatalyst has been evaluated. © 1993 John Wiley & Sons, Inc.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 33 (1995), S. 2787-2793 
    ISSN: 0887-624X
    Keywords: Ziegler-Natta catalysis ; EPDM synthesis ; metallocene catalyst ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 4-Vinylcyclohexene (VCH) and cyclooctadiene (COD) were investigated as termonomers in EPDM (ethylene/propylene/diene) synthesis by using rac-ethylenebis (1-η5-indenyl) zir-conium dichloride (1) as a catalyst precursor. Homopolymerizations of VCH, vinylcycloh-exane and cyclohexene were compared. The parameter Kπκp, which is the apparent rate constant for Ziegler-Natta polymerization, is about the same for VCH and vinylcyclohexanebut is 10 times smaller for cyclohexene. Therefore, the linear olefinic double bond is more active than the cyclic internal double bond. VCH reduces ethylene polymerization rate but not propylene polymerization rate in copolymerizations. In terpolymerizations, VCH tends to suppress ethylene incorporation especially at elevated polymerization temperature and Lowers the polymer MW by about two-fold. COD has very low activity as a termonomer. © 1995 John Wiley & Sons, Inc.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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