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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 82 (1985), S. 4965-4976 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: This report belongs to a series concerned with the correlation of photolysis bands observed in electronic transition spectra of simple molecules with their dissociation products. In this work a time-delayed, double resonance application of optical impedance spectroscopy was used for the study of the state selective photolysis of Cs2 excited in the yellow range of visible wavelengths. Two independently tunable dye lasers were synchronously pulsed, the first being used to dissociate the constituents of the sample along the various possible channels and the second, delayed pulse being used to identify the products by exciting them selectively into easily detected Rydberg states. The time between photolysis and detection could be varied, starting from a value too short to permit collisional mixing or radiative cascading of the products. Particular attention was paid to the photolytic production of the fine structure components of the first and second electronically excited state of atomic cesium and to the subsequent processes which tended to degrade the selectivity produced in the initial distributions of product populations among the available states. Data were fit to a quantitative model from which rate coefficients could be extracted for various mixing processes. Reported here is what appears to be a first value for the fine-structure mixing cross section (5 2D5/2→5 2D3/2) of 17 A(ring)2±60%. In addition a delayed process for the selective production of Cs(5 2D) atoms was found to result from the excitation of a state having a lifetime less than 100 ns that is tentatively identified as a molecular state correlated with Cs(5 2D), possibly 5d 3Δu.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 67 (1996), S. 4399-4400 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A fast high voltage switch to discharge a capacitive load using a stack of bipolar junction transistors is described. The switch operating at a voltage of 3.5 kV has a fall time (90%–10%) of ∼2 ns. With a capacitive load (pockel cell) the pulse fall time increases to 6 ns. The life of the stack is 〉50 million shots. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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