ISSN:
1089-7690
Quelle:
AIP Digital Archive
Thema:
Physik
,
Chemie und Pharmazie
Notizen:
The C1s core photoelectron spectra of a series of alkene molecules, ethene, propene, 1-butene, cis and trans 2-butene, 2-methyl-propene, and 1-pentene are discussed. The experimental spectra are assigned using intermediate neglect of differential overlap-configuration interaction (INDO-CI) calculations and comparative discussions. It is shown that hyperconjugation is a useful concept in the assignment of the transitions. INDO-CI is shown to give a reasonable description of the low energy part of the spectra. The results are used in the discussion of molecular models for the interpretation of the electronic structure of polyacetylene.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1063/1.462633
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