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  • 1
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: An experimental setup is described, which is used to multi-ionize neutral clusters and to study their stability and the importance of different decay processes. Clusters are ionized in collisions with slow multiply charged ions (projectile charge z ranging from 1 to 30, kinetic energies ranging from 1 to 20 keV/charge). Both ion and cluster beamlines, as well as the characteristics of the analysis and detection systems, are described. Collisions with highly charged ions such as Ar8+ or Xe30+ turn out to be efficient tools in preparing clusters in high charge states without increasing significantly their internal temperature. Measurements performed in coincidence with the number of electrons stabilized by the projectile ion after the collision allowed us to control the charge and the excitation energy of the ionized system. The efficiency of the method is demonstrated for sodium clusters and C60 molecules. © 1999 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 65 (1994), S. 3344-3353 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A modified version of the classic Wiley–McLaren time-of-flight mass spectrometer (TOFMS) is presented here. Owing to a second-order compensation of the initial position effect, a mass resolution m/δm higher than 2000 is obtained with large ion volumes, of the order of 0.2 cm3 for Na+55 (1265 a.m.u.). Sodium clusters Na+n with n up to 530 ((approximately-equal-to)12200 a.m.u.) are separated. The spectrometer can be used for the analysis of ionized clusters in a mass range from 1 to about 20000 a.m.u. as well as for the measurement of the kinetic energy of molecular fragments after a Coulomb explosion of a molecule. The performance of this spectrometer is demonstrated with sodium clusters and molecules.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1434-6079
    Keywords: PACS: 36.40.-c Atomic and molecular clusters – 32.10.Dk Electric and magnetic moments, polarizability – 31.15.Ew Density functional theory
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract. We have measured the static dipole polarizability of lithium and sodium clusters (n=1-22). Values measured for sodium are in agreement with previous experiments. While the polarizability per atom for sodium clusters decreases slowly as a function of the cluster size, a sharp decrease between sizes 1 and 4 is observed for lithium clusters. Experimental values are compared to Density Functional Theory (DFT/PW91) calculations. The size evolutions for sodium and lithium cluster polarizabilities are well reproduced by our calculations. The sharp decrease observed for small lithium clusters is discussed in terms of electronic density.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1434-6079
    Keywords: PACS. 36.40.Wa Charged clusters – 34.50.Bw Energy loss and stopping power
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract: In an experimental study, the multi-ionisation of metallic clusters (Nan) has been analysed in collisions with light ions in low charge states (H+, He+, He2+, O3+) at collision velocities below 1 a.u. Cluster ions are produced in charge states up to 5+. The average charge of the nano-particles is found to increase linearly with the variation of projectile velocity and the square of the effective projectile charge, well in agreement with the electronic stopping power of the bulk material. A fraction of 50% to 30% of the total projectile energy loss (decreasing with velocity) is transferred into vibrational modes in good agreement with recent theoretical predictions.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 9 (1999), S. 119-122 
    ISSN: 1434-6079
    Keywords: PACS: 61.46.+w Clusters, nanoparticles, and nanocrystalline materials – 36.40.Qv Stability and fragmentation of clusters
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract. Na clusters in the size range of 50–400 atoms are led to evaporate in a heat bath with controlled temperature. For specific cluster sizes just above closed shells, decay rates are measured as a function of temperature. They agree with an Arrhenius law and allow absolute separation energies to be extracted.
    Type of Medium: Electronic Resource
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