Abstract
The x-ray photoemission spectra of the valence bands of Hf metal and of several HfC x N y O z compounds have been measured and are compared to existing band structure calculations. The density of states at the Fermi energy of the HfC x N y O z compounds correlates strongly to their superconducting transition temperatureT c . A calculation of theT c values within the frame work of strong coupling superconductors indicates that the phonon spectrum and the electron phonon interaction is approximately constant within the series HfC x N y O z .
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Toth, L.E.: Transition Metal Carbides and Nitrides, New York: Academic Press 1971; see also for earlier references
Mattheiss, L.F.: Phys. Rev. B5, 315 (1972)
Chadi, D.J., Cohen, M.L.: Phys. Rev. B10, 496 (1974)
Zbasnik, J., Toth, L.E.: Phys. Rev. B8, 452 (1973)
Neckel, A., Rastl, P., Eibler, R., Weinberger, P., Schwarz, K.: J. Phys. C9, 579 (1976)
Ihara, H., Hirabayashi, M., Nakagawa, H.: Phys. Rev. B14, 1707 (1976)
Gupta, M., Freeman, A.J.: Phys. Rev. B14, 5205 (1976)
Weber, W.: Phys. Rev. B8, 5082 (1973); Phys. Rev. B8, 5093 (1973)
Hanke, W., Hafner, J., Bilz, H.: Phys. Rev. Letters37, 1560 (1976)
Höchst, H., Steiner, P., Hüfner, S.: J. Phys. F7, L 309 (1977); Z. Physik B30, 145 (1978)
For more details see: Politis, C.: KFK report 2168, Kernforschungszentrum Karlsruhe, 1975
Schneider, H., Nold, E.: Z. Anal. Chem.269, 113 (1974)
Jepsen, O., Andersen, O.K., Mackintosh, A.R.: Phys. Rev. B12, 3084 (1975)
Höchst, H., Hüfner, S., Goldmann, A.: Phys. Lett.57 A, 265 (1976)
Höchst, H., Hüfner, S., Goldmann, A.: Z. Physik B26, 133 (1977)
Pendry, J.B., Hopkinsen, J.F.L.: J. Phys. F8, 1009 (1978)
Nemoshkalenko, V.V., Aleshin, V.G., Kucherenko, Yu.N.: J. Electron Spectrosc. Relat. Phenon.13, 361 (1978); see also for earlier references concerning the modulation of the photoexcitation cross section
Wertheim, G.K., Citrin, P.H.: Topics in Applied Physics Vol.26, Cardona, M., Ley, L. (eds.) Berlin, Heidelberg, New York: Springer 1978; see also for earlier references in this field
Steiner, P., Höchst, H., Hüfner, S.: Z. Physik B30, 129 (1978)
Schwarz, K.: private communication
Scofield, J.H.: J. Electron Spectrosc. Rel. Phenom8, 129 (1976)
Stroumonis, M.E., Faunce, C.A.: Z. anorg. allg. Chem.353, 329 (1967)
McMillan, W.L.: Phys. Rev.167, 331 (1968)
Gladstone, G., Jensen, M.A., Schriefer, J.R.: Superconductivity, Vol. II, Parks, R.D. (ed.) New York: Marcel Dekker 1969; see also for other articles on the subject
Bennemann, K.H., Garland, J.W.: AIP Conf. Proc. No.4, 104 (1972)
Smith, N.G., Gläser, W.: Phys. Rev. Lett.25, 1611 (1970); Phys. Rev. Lett.29, 353 (1972)
Barukhovich, A.S.: phys. stat. sol. (a)46, 11 (1978)
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Steiner, P., Höchst, H., Schneider, J. et al. The XPS valence band spectra of Hf metal and HfC x N y O z compounds and the correlation to their superconductivity. Z Physik B 33, 241–250 (1979). https://doi.org/10.1007/BF01323499
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DOI: https://doi.org/10.1007/BF01323499