Abstract
Cluster abundance of Li + n (n≤19), Na + n (n≤25), Si z+ n (n≤8 forz=1, 3≤n≤7 forz=2), Ge z+ n (n≤11 forz=1, 3≤n≤9 forz=2,n=4 forz=3), Sn z+ n (n≤7 forz=1, 3≤n≤9 forz=2,n=4 forz=3) and Pb z+ n (n≤6 forz=1, 5≤n≤7 forz=2) ejected from a liquid metal ion source has been investigated by mass spectrometry. The abundance spectra of alkali metal clusters showed distinct maxima and steps atn=3, 7, 9, 13 and 19 for Li, and atn=3, 5, 11, 13 and 19 for Na. Mass spectra of Si, Ge and Sn clusters were very similar each other, showing intensity drops aftern=4 and 6 (and alson=10 for Ge) for singly charged clusters. The magic numbers observed are discussed in terms of stability of charged clusters.
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Mühlbach, J., Pfau, P., Sattler, K., Recknagel, E.: Z. Phys. B-Condensed Matter47, 233 (1982)
Knight, W.D., Clemenger, K., de Heer, W.A., Saunders, W.A., Chou, M.Y., Cohen, M.L.: Phys. Rev. Lett.52, 2141 (1984)
Katakuse, I., Ichihara, T., Fujita, Y., Matsuo, T., Sakurai, T., Matsuda, H.: Int. J. Mass Spectrom. Ion Proc.67, 229 (1985)
Joyes, P., Sudraud, P.: Surf. Sci.156, 451 (1985)
Noda, T., Okutani, T., Yagi, K., Tamura, H., Okano, H., Watanabe, H.: Int. J. Mass Spectrom. Ion Phys.46, 15 (1983)
Boustani, I., Pewestorf, W., Fantucci, P., Bonačić-Koutecký, V., Koutecký, J.: Phys. Rev. B35, 9437 (1987)
Rao, B.K., Khanna, S.N., Jena, P.: Phys. Rev. B36, 953 (1987)
Van de Walle, J., Joyes, P.: Phys. Rev. B32, 8381 (1985)
Minami, K., Saito, Y., Noda, T.: Rapid Commun. Mass Spectrom.2, 115 (1988)
Brown, W.L., Freeman, R.R., Raghavachari, K., Schluter, M.: Science235, 860 (1987)
Dixon, A., Colliex, C., Ohana, R., Sudraud, P., Van de Walle, J.: Phys. Rev. Lett.46, 865 (1981)
Komuro, M.: In: Proc. Inter. Ion Engineering Congress, -IS-IAT'83-, Kyoto (1983), Takagi, T. (ed.), pp. 337–348
Noda, T., Okutani, T., Tamura, H.: Oyo Butsuri54, 935 (1985) [in Japanese]
Saito, Y., Yamauchi, K., Mihama, K., Noda, T.: Jpn. J. Appl. Phys.21, L396 (1982)
Tsong, T.T.: Appl. Phys. Lett.45, 1149 (1984)
Joyes, P., Van de Walle, J.: J. Phys. B18, 3805 (1985)
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Saito, Y., Noda, T. Cluster cations ejected from liquid metal ion source: alkali metals (Li, Na) and group IV elements (Si, Ge, Sn, Pb). Z Phys D - Atoms, Molecules and Clusters 12, 225–227 (1989). https://doi.org/10.1007/BF01426943
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DOI: https://doi.org/10.1007/BF01426943