Abstract
Recently we have observed [1–4] photodissociation of neutral van der Waals clusters induced by visible laser light using coaxial interaction between the beams. Because of possible artifacts we have repeated here this experiment in a crossed beam configuration. The present results confirm the occurrence of this photodissociation effect. We suggest tentatively that excitation via Raman scattering is the origin of this phenomenon.
References
A. Stamatovic, F. Howorka, P. Scheier and T. D. Märk, Chem. Phys. Lett.,145, 95 (1988)
A. Stamatovic, P. Scheier, F. Howorka and T.D. Märk, Int. J. Mass Spectrom. Ion Proc.83, R1 (1988)
A. Stamatovic, F. Howorka and T.D. Märk, Chem. Phys. Lett., in print (1989)
T.D. Märk, A. Stamatovic, F. Howorka and P. Scheier, Chem. Phys. Lett.,149, 230 (1988)
See for instance T.E. Gough, R.E. Miller and G. Scoles, J. Chem. Phys.,69, 1588 (1978); J.M. Lisy, A. Tramer, M.F. Vernon and Y.T. Lee, J. Chem. Phys.,75, 4722 (1981); D.H. Levy, Adv. Chem. Phys.,47, 323 (1981); J. Geraedts, S. Stolte and J. Reuss, Helv. Phys. Acta,56, 529 (1983)
Except those van der Waals complexes, like for instance ArI2, where an electronic transition of the uncomplexed molecule lies in the visible range [5]
T.D. Märk, A. Stamatovic, F. Howorka, P. Scheier and G. Walder, Nuovo Cimento, in print (1989)
R. Rechsteiner, R. Monot, L. Wöste, J.M. Zellweger and H. van den Bergh, Helv. Phys. Acta,54, 282 (1981)
D. Bassi (Priv. communication 1989)
H.P. Godfried and I.F. Silvera, Phys. Rev.A27, 3008 (1983)
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Walder, G., Howorka, F., Stamatovic, A. et al. Photodissociation of neutral argon clusters with visible laser light: new experimental evidence. Z Phys D - Atoms, Molecules and Clusters 13, 179–180 (1989). https://doi.org/10.1007/BF01398588
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DOI: https://doi.org/10.1007/BF01398588