Abstract
We report a method for the synthesis of sodium or potassium colloids at room temperature under nitrogen. The colloids, formed within a protective matrix of alkali metal halide and a polysilane polymer, are remarkably air-stable. The UV-visible and EPR spectroscopic characterisation of the colloids is described.
Similar content being viewed by others
References
Hughes, A.E. & Jain, S.C.: Adv. Phys.28, 717 (1979)
Xu, B. & Kevan, L.: J. Chem. Soc., Faraday Trans.87, 2843 (1991)
Guy, S.C.; Edmonds, R.N. & Edwards, P.P.: J. Chem. Soc. Faraday II,81, 937 (1985)
Wurtz, A.: Justus Liebigs Ann. Chem.96, 364 (1855)
Benfield, R.E.; Cragg, R.H.; Jones, R.G. & Swain, A.C.: Nature353, 340 (1991)
West, R.: J. Organomet. Chem.300, 327 (1986)
Michl, J. & Miller, R.D.: Chem. Rev.89, 1359 (1989)
Cragg, R.H.; Jones, R.G.; Swain, A.C. & Webb. S.J.: J. Chem. Soc., Chem. Commun. 1147 (1990)
Jones, R.G.; Benfield, R.E.; Cragg, R.H. & Swain, A.C.: J. Chem. Soc., Chem. Commun. 112 (1992)
Smithard, M.A. & Tran, M.Q.: Helv. Phys. Acta46, 869 (1974)
Doyle, W.T.: Proc. Phys. Soc.75, 649 (1960)
Radchenko, I.S.: Optika i Spektroskopiya25, 899 (1968); Optics and Spectroscopy25, 500 (1968)
Scott, A.B.; Smith, W.A. & Thompson, M.A.: J. Phys. Chem.57, 757 (1953)
Compton, W.D. & Schulman, J.H.: “Color Centers in Solids” (MacMillan, New York) p29 & pp52–53 (1962)
Vitol, A.Ya.; Kharakhash'yan, E.G.; Cherkasov, F.G. & Shvarts, K.K.: Fiz. Tverd. Tela13, 2133 (1971); Soviet Physics — Solid State13, 1787 (1972)
Gordon, D.A.: Phys. Rev.B13, 3738 (1976)
McMillan, R.C.: J. Phys. Chem. Solids25, 773 (1964)
Seidel, H. & Wolf, H.C.: in “Physics of Color Centers”, ed. Fowler, W.B (Academic Press, New York/London), 537 (1968)
Doyle, W.T.: Phys. Rev.111, 1067 (1958)
Jones, R.G.; Benfield, R.E.; Cragg, R.H.; Swain, A.C. & Webb, S.J.: Macromolecules, submitted for publication (1992)
Eadon, D.G.: Ph.D. Thesis, University of Kent (1988)
Creighton, J.A. & Eadon, D.G.: J. Chem. Soc., Faraday Trans.,87, 3881 (1991)
Benfield, R.E.; Jones, R.G.; Cragg, R.H. & Swain, A.C.: J. Chem. Soc., Chem. Commun. 1022 (1992)
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Benfield, R.E., Cragg, R.H., Jones, R.G. et al. Low-energy synthesis of air-stable alkali metal colloids in a polymer/alkali halide matrix. Z Phys D - Atoms, Molecules and Clusters 26 (Suppl 1), 18–20 (1993). https://doi.org/10.1007/BF01425604
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01425604