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Electronic structures and reactivities of derivatives of 1,4-dihydropyridines. 1. 1-Methyl-3-carbamidopyridinyl radical and 1-methyl-3-carbamidopyridinium cation

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The physicochemical properties and electronic and three-dimensional structures of the products of transformations of 1-methyl-1,4-dihydronicotinamide were calculated within the MINDO/3 approximation. The problems associated with their reactivities in reactions involving electron and hydrogen-atom transfer, as well as the problems of “hydride” transfer in chemical reactions, are discussed.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Academy of Sciences of the Ukrainian SSR, 252660, Kiev

    A. M. Nesterenko, N. I. Buryak, O. M. Polumbrik & A. A. Yasnikov

Authors
  1. A. M. Nesterenko
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  2. N. I. Buryak
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  3. O. M. Polumbrik
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  4. A. A. Yasnikov
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1640–1644, December, 1987.

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Nesterenko, A.M., Buryak, N.I., Polumbrik, O.M. et al. Electronic structures and reactivities of derivatives of 1,4-dihydropyridines. 1. 1-Methyl-3-carbamidopyridinyl radical and 1-methyl-3-carbamidopyridinium cation. Chem Heterocycl Compd 23, 1320–1324 (1987). https://doi.org/10.1007/BF00472256

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  • DOI: https://doi.org/10.1007/BF00472256

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