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Stereospecificity of spin-spin coupling constants (SSCC) of 1H, 15N, and 19F nuclei in substituted 2,2-bis(trifluoromethyl)aziridines

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

1-Chloro-, 3-methyl-, 1-chloro-3-cyano-, 1-carbomethoxymethoxy-3-methyl-, and 1-carboxymethoxy-3-methyl-2,2-bis(trifluoromethyl)aziridines were synthesized for the first time. Criteria for distinguishing cis- and trans-3-substituted and 1,3-disubstituted 2,2-bis(trifluoromethyl)aziridines from the parameters of the 1H, 13C, and 19F NMR spectra were found.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, 117334, Moscow

    R. G. Kostyanovskii, G. K. Kadorkina, I. I. Chervin & I. K. A. Romero Maldonado

Authors
  1. R. G. Kostyanovskii
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  2. G. K. Kadorkina
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  3. I. I. Chervin
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  4. I. K. A. Romero Maldonado
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Additional information

Communication 64 from the series “Asymmetric nitrogen.” See [1] for communication 63.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 757–765, June, 1988.

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Kostyanovskii, R.G., Kadorkina, G.K., Chervin, I.I. et al. Stereospecificity of spin-spin coupling constants (SSCC) of 1H, 15N, and 19F nuclei in substituted 2,2-bis(trifluoromethyl)aziridines. Chem Heterocycl Compd 24, 616–624 (1988). https://doi.org/10.1007/BF00475594

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  • DOI: https://doi.org/10.1007/BF00475594

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