Conclusions
From the analysis we have presented here, we can state that the mutual influence of ions in simple diatomic and triatomic molecules essentially comes down to polarization effects similar to the Stark shift of levels. An expression for the Stark shift, obtained within the framework of perturbation theory, is valid only for weak fields. However, experiments indicate that phenomena similar to the Stark shift of levels occur for rather strong intramolecular fields as well.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
T. Koopmans, Physika (Utrecht),1, 104 (1934).
P. G. Val'kov, I. S. Gotkis, V. N. Belyaev, and K. S. Krasnov, Summaries of Papers from 7th All-Union Symposium on the Chemistry of Inorganic Fluorides [in Russian], Leninabad (1984).
V. N. Belyaev, N. L. Lebedeva, and K. S. Krasnov, Summaries of Papers from 7th All-Union Symposium on the Chemistry of Inorganic Fluorides [in Russian], Leninabad (1984).
V. N. Belyaev, N. L. Lebedeva, K. S. Krasnov, and L. V. Gurvich, Summaries of Papers from 9th All-Union Conference on Calorimetry and Chemical Thermodynamics [in Russian], Tbilisi (1982), p. 323.
V. N. Belyaev, N. L. Lebedeva, K. S. Krasnov, and L. V. Gurvich, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol.,27 (1984).
J. Vogt and C. Pascual, Int. J. Mass Spectrom. Ion Phys.,9, 441 (1974).
D. L. Hildenbrand, Int. J. Mass Spectrom. Ion Phys.,4, 75 (1970).
D. L. Hildenbrand, J. Chem. Phys.,66, 3526 (1977).
P. D. Kleinschmidt and D. L. Hildenbrand, J. Chem. Phys.,68, 2819 (1978).
D. L. Hildenbrand and E. Murad, J. Chem. Phys.,44, 1524 (1966).
D. L. Hildenbrand, J. Chem. Phys.,48, 3657 (1968).
V. P. Glushko (editor), Handbook: Thermodynamic Properties of Individual Substances [in Russian], Nauka, Moscow (1978–1983).
Ch. Ryzlewich et al., Chem. Phys.,71, 389 (1982).
T. A. Johnston, C. R. Webster, and R. N. Zare, J. Chem. Phys.,75, 5575 (1981).
N. F. Mott and I. A. Sneddon, Wave Mechanics, Dover, New York (1948).
G. A. Kasabov and V. V. Eliseev, Spectroscopic Tables for Low-Temperature Plasma [in Russian], Atomizdat, Moscow (1973).
A. A. Radtsig and B. M. Smirnov, Handbook of Atomic and Molecular Physics [in Russian], Atomizdat, Moscow (1980).
S. Kindt et al., Chem. Phys. Lett.,103, 241 (1983).
N. Jonjou, G. F. Adams, and D. R. Varkony, J. Chem. Phys.,79, 4376 (1983).
A. W. Potts and W. C. Price, Phys. Scr.,16, 191 (1977).
J. Berkowitz, in: Alkali Halide Vapors: Structure, Spectra and Reaction Dynamics, Academic Press, New York (1979), p. 155.
E. P. F. Lee and A. W. Potts, Proc. R. Soc. London, Ser. A,365, 395 (1979).
S. P. Konovalov and V. G. Solomonik, Zh. Strukt. Khim.,23, 90 (1982).
Author information
Authors and Affiliations
Additional information
Translated from Zhurnal Strukturnoi Khimii, Vol. 26, No. 5, pp. 27–34, September–October, 1985.
Rights and permissions
About this article
Cite this article
Gotkis, I.S., Belyaev, V.N., Val'kov, P.G. et al. Ionization potentials and structure of simple ionic compounds. J Struct Chem 26, 674–680 (1985). https://doi.org/10.1007/BF00773259
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00773259