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An investigation of the structure and reactivity of some stable radicals

A report of the general meeting of the Division of Chemical Science, the Academy of Sciences of the USSR, Moscow, June 22, 1961

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The stable radicals from 40 antioxidants (substituted phenols and aromatic amines) were obtained by oxidation. The EPR spectra of these radicals were investigated.

  2. 2.

    These radicals can remove hydrogen from solvents. The kinetics of this reaction were studied at various temperatures. In this way these radicals can serve as a medium for the investigation of the reactivity of various bonds.

  3. 3.

    The absorption spectra of some of the antioxidants and their radicals were taken in the ultraviolet and infrared regions.

  4. 4.

    The radicals obtained by the oxidation of ionol were separated and identified by paper chromatography.

  5. 5.

    A classification of stable radicals is suggested.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences, USSR

    M. B. Neiman & A. L. Buchachenko

Authors
  1. M. B. Neiman
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  2. A. L. Buchachenko
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Neiman, M.B., Buchachenko, A.L. An investigation of the structure and reactivity of some stable radicals. Russ Chem Bull 10, 1624–1630 (1961). https://doi.org/10.1007/BF00911429

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  • DOI: https://doi.org/10.1007/BF00911429

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