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Chromatographic separation of the radicals formed in oxidation of hydrated 2,2,2-trimethyl quinolines

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    Oxidation of partly hydrated 2,2,4-trimethylquinolines forms a complex mixture of radicals of various structures. It is possible to separate this complex mixture chromatographically and get out the individual free radicals.

  2. 2.

    EPR and infrared spectroscopy methods make it possible to identify the structure of a number of the radicals and indicate what the next transformations will be.

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Literature cited

  1. A. L. Buchachenko and M. B. Neiman, Dokl. AN SSSR,139, 916 (1961).

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  2. A. L. Buchachenko, Dissertation, Moscow (1961).

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences, USSR

    A. A. Medzhidov, A. L. Buchachenko, É. G. Rozantsev & M. B. Neiman

Authors
  1. A. A. Medzhidov
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  2. A. L. Buchachenko
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  3. É. G. Rozantsev
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  4. M. B. Neiman
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Medzhidov, A.A., Buchachenko, A.L., Rozantsev, É.G. et al. Chromatographic separation of the radicals formed in oxidation of hydrated 2,2,2-trimethyl quinolines. Russ Chem Bull 12, 1572–1576 (1963). https://doi.org/10.1007/BF00845780

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  • DOI: https://doi.org/10.1007/BF00845780

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