Conclusions
-
1.
The processes involved in the solvation of Et3GeLi by donating solvents (L) in benzene were studied by the PMR method. The preferred stoichiometry and the spectral parameters of the Et3GeLi·nL complexes which form were determined.
-
2.
It was shown that the structure of the ion pair of Et3GeLi in donating solvents at various temperatures can be determined from the PMR spectra.
Similar content being viewed by others
Literature cited
D. A. Bravo-Zhivotovskii, I. D. Kalikhman, O. A. Kruglaya, and N. S. Vyazankin, Izv. Akad. Nauk SSSR, Ser. Khim., 1934 (1977).
D. A. Bravo-Zhivotovskii, I. D. Kalikhman, O. A. Kruglaya, and N. S. Vyazankin, Izv. Akad. Nauk SSSR, Ser. Khim., 1841 (1979).
E. G. Bulten and G. J. Noltes, J. Organomet. Chem.,29, 397 (1971).
E. N. Gur'yanova, I. P. Gol'dshtein, and I. P. Romm, The Donor-Acceptor Bond [in Russian], Khimiya (1973).
J. W. Burley and R. N. Young, J. Chem. Soc., B 1018 (1971).
N. Hirota, J. Am. Chem. Soc.,90, 3603 (1968).
M. R. Arick, J. A. M. van Brockhoven, F. W. Pijers, and E. de Boer, J. Am. Chem. Soc.,94, 7931 (1972).
W. Martin, A. E. Alegria, and G. R. Stevenson, J. Am. Chem. Soc.,98, 7955 (1976).
S. Pasynkiewez and Z. Buzkovski, J. Organomet. Chem.,22, 525 (1970).
M. W. G. Bolster, Z. Anorg. Allg. Chem.,434, 78 (1977).
R. N. Shchelokov, A. Yu. Tsivadze, J. M. Orlova, and G. V. Podnebesnova, Inorg. Nucl. Chem. Lett.,13, 375 (1977).
V. Gutmann, Coordination Chem. Rev.,18, 225 (1976).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 53–56, January, 1980.
Rights and permissions
About this article
Cite this article
Kalikhman, I.D., Bravo-Zhivotovskii, D.A., Pertsikov, B.Z. et al. Investigation of the ionic forms of triethylgermyllithium in solutions by PMR spectroscopy. Russ Chem Bull 29, 43–47 (1980). https://doi.org/10.1007/BF00951875
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00951875