Conclusions
The reaction of chloro-substituted vinyl phenyl ethers with dichlorocarbene generated by the thermolysis of phenyl(trichloromethyl)mercury leads to the corresponding gem-dichlorocyclopropyl derivatives while the reaction of cis-β-chlorovinyl phenyl ether with chloroform and alkali under phase transfer catalysis conditions gives α-trichloromethyl-β-chloroethyl phenyl ether.
This is a preview of subscription content, log in via an institution to check access.
Literature cited
M. Makosza and M. Wawrzyniewiez, Tetrahedron Lett., 4659 (1965).
A. N. Nesmeyanov, R. Kh. Freidlina, and F. K. Velichko, Dokl. Akad. Nauk SSSR,114, 557 (1957).
W. Weber and G. Hokel, in: Phase Transfer Catalysis in Organic Synthesis [Russian translation], Mir, Moscow (1980), p. 36.
D. Seyferth and J. M. Burlith, J. Am. Chem. Soc.,87, 4259 (1965).
Author information
Authors and Affiliations
Additional information
Deceased.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 222–224, January, 1985.
Rights and permissions
About this article
Cite this article
Shostakovskii, M.F., Mochalov, V.N., Filippov, O.F. et al. Dichlorocyclopropanation of chloro-substituted vinyl phenyl ethers. Russ Chem Bull 34, 210–211 (1985). https://doi.org/10.1007/BF01157363
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01157363