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Pyrolysis of 8,8-dimethyl-8-sila-2,3,4,5-tetrathiabicyclo[4.3.0]nonane

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The main products of the pyrolysis of 8,8-dimethyl-8-sila-2,3,4,5-tetrathiabicycIo-[4.3.0]nonane at 400‡ are 1,1-dimethylsilacyclopent-3-ene and 1,1-dimethyl-1-sila-2-thiacyclo-hexa-3, 5-diene, and at 600‡ carbon disulfide and thiophene; silacyclopentene is the sole reaction product, characteristic for the mass-spectrometric decomposition of the initial tetrasulfide.

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow

    E. A. Chernyshev, O. V. Kuz'min, A. V. Lebedev, V. G. Zaikin & A. I. Mikaya

Authors
  1. E. A. Chernyshev
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  2. O. V. Kuz'min
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  3. A. V. Lebedev
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  4. V. G. Zaikin
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  5. A. I. Mikaya
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No, 4, pp. 902–905, April, 1986.

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Chernyshev, E.A., Kuz'min, O.V., Lebedev, A.V. et al. Pyrolysis of 8,8-dimethyl-8-sila-2,3,4,5-tetrathiabicyclo[4.3.0]nonane. Russ Chem Bull 35, 821–824 (1986). https://doi.org/10.1007/BF00954237

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  • DOI: https://doi.org/10.1007/BF00954237

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