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Investigation of the alkylation ability of silylated nitroalcohols

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Abstract

β-Nitrosubstituted trimethylsilylated alcohols RCH2-O-SiMe3 [R=N(NO2)Me, C(NO2)Me2, C(NO2)2Me, C(NO2)3] have been studied. It has been shown that the trimethylsiloxy group is sufficiently reactive only in the N-nitro derivative in which it can be replaced by a chlorine atom or dimethylamino group upon the action of trimethylchlorosilane or pentamethyldisilazane, respectively.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp, 117913, Moscow, Russian Federation

    E. T. Apasov, A. V. Kalinin, S. L. Ioffe & V. A. Tartakovskii

Authors
  1. E. T. Apasov
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  2. A. V. Kalinin
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  3. S. L. Ioffe
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  4. V. A. Tartakovskii
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Translated fromIzvestiya Akademii Nauk. Seriya Khimkheskaya, No. 7, pp. 1319–1320, July, 1993.

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Apasov, E.T., Kalinin, A.V., Ioffe, S.L. et al. Investigation of the alkylation ability of silylated nitroalcohols. Russ Chem Bull 42, 1262–1263 (1993). https://doi.org/10.1007/BF00702022

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  • DOI: https://doi.org/10.1007/BF00702022

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