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Kinetic method of applying labeled atoms in the investigation of complex chemical and biochemical processes Communication 6. Rates of formation and transformation of acetaldehyde, carbon monoxide, and carbon dioxide in the oxidation of propene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    It was shown by the blowing method that acetaldehyde can be determined polarographically in the products of the oxidation of propene.

  2. 2.

    It was shown that at temperature up to 387°, no hydrogen transfer occurs in alcohol-acetaldehyde mixtures.

  3. 3.

    It was shown that most of the carbon dioxide produced in the oxidation of propene is not formed by the oxidation of carbon monoxide.

  4. 4.

    It was shown that in the oxidation of propene, acetaldehyde is formed and consumed at comparable rates.

  5. 5.

    It was shown that in the cool-flame zone, about 50% of the carbon dioxide and 30% of the carbon monoxide are formed from the carbonyl group of acetaldehyde.

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Literature cited

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Authors and Affiliations

  1. Institute of Chemical Physics of the Academy of Sciences of the USSR, USSR

    M. B. Neiman, V. Ya. Efremov, N. K. Serdyuk & A. F. Lukovnikov

Authors
  1. M. B. Neiman
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  2. V. Ya. Efremov
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  3. N. K. Serdyuk
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  4. A. F. Lukovnikov
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Neiman, M.B., Efremov, V.Y., Serdyuk, N.K. et al. Kinetic method of applying labeled atoms in the investigation of complex chemical and biochemical processes Communication 6. Rates of formation and transformation of acetaldehyde, carbon monoxide, and carbon dioxide in the oxidation of propene. Russ Chem Bull 5, 397–403 (1956). https://doi.org/10.1007/BF01191836

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  • DOI: https://doi.org/10.1007/BF01191836

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