Abstract
General analytical expressions are obtained for the potential energy of the interaction between an electron and a molecule and the 2L-pole electric moments of the molecules by the Hartree-Fock-Rutan method. These formulas are used for a machine calculation of the interaction potential between an electron and hydrogen and nitrogen molecules with different electron distances from these molecules and also of the electric multipole moments of a series of diatomic molecules with L = 0, 1, 2, 3.
Similar content being viewed by others
Literature cited
H. Bethe, Quantum Mechanics [Russian translation], Mir, Moscow (1965).
I. I. Guseinov, Phys. Rev. A,22, 369 (1980).
I. I. Guseinov, J. Phys. B,3, 1399 (1970).
I. I. Guseinov, Chem. Phys.,67, 3837 (1977).
E. Condon and G. H. Shortley, Theory of Atomic Spectra, Cambridge University, Press, New York (1935).
L. D. Landau and E. M. Lifshitz, Field Theory [in Russian], Nauka, Moscow (1967).
S. Fraga and B. J. Ransil, J. Chem. Phys.,35, 1967 (1961).
B. J. Ransil, Rev. Mod. Phys.,32, 245 (1960).
P. E. Cade and A. C. Wahl, At. Data Nucl. Data Tables,13, 339 (1974).
P. E. Cade and W. M. Huo, At. Data Nucl. Data Tables,12, 415 (1973);15, No. 1 (1975).
F. H. M. Faisal, J. Phys. B,3, 636 (1970).
K. F. W. Bader, I. Keaveny, and P. E. Cade, J. Chem. Phys.,47, 3381 (1967).
N. F. Stepanov, V. Ya. Simkin, et al., Vesta. Mosk. Univ., Khim., No. 4, 484 (1978).
A. A. Radtsig and B. M. Smirnov, Handbook on Atomic and Molecular Physics [in Russian], Atomizdat, Moscow (1980).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 3, pp. 52–56, March, 1985.
Rights and permissions
About this article
Cite this article
Guseinov, I.I., Mursalov, T.M. & Aliev, V.T. Potential energy of interaction between an electron and a molecule on the basis of slater atomic orbitals. Soviet Physics Journal 28, 220–224 (1985). https://doi.org/10.1007/BF00895909
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00895909