Abstract
The so-called anode effect, particularly important in industrial alumina electrolysis, has mostly been interpreted as the consequence of altered wettability of the electrode surface by the melt. By means of a mathematical model assuming isolated large bubbles in contact with the electrode it is shown that the anode effect is the result of the combined action of fluid dynamics and wettability. The interpretation of the incipience of the anode effect obtained by means of a previous, completely different mathematical model is confirmed. The theoretical results are compared with experimental data by various authors.
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Vogt, H. The anode effect as a fluid dynamic problem. Journal of Applied Electrochemistry 29, 137–145 (1999). https://doi.org/10.1023/A:1003477004486
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DOI: https://doi.org/10.1023/A:1003477004486