Abstract
A series of compounds all containing the ferrous hexaquo complex were investigated by Mössbauer spectroscopy at 4.2K and in magnetic fields up to 5T and far infrared techniques. The results are interpreted in terms of a T2g ligand field model for which normal distortions of the water octahedron are used as parameters. The ferrous hexaquo complex can be described in all compounds by the same covalency, spin-orbit coupling and hyperfine coupling constants.
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Doerfler, R., Leupold, O., Nagy, D.L. et al. Ligand field and hyperfine interaction of the [Fe(H2O)6]2+ complex in different compounds. Hyperfine Interact 16, 831–835 (1983). https://doi.org/10.1007/BF02147376
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DOI: https://doi.org/10.1007/BF02147376