Abstract
Pyrene, as a fluorescence probe, has been used to study the cyclodextrin complexation process in the presence of different alcohols. The complex formation as well as the hydrophobicity of the cyclodextrin interior can be significantly influenced by the introduction of alcohols. The alcoholic alkyl group and the primary and secondary hydroxyl groups of the cyclodextrin proved to be the determining factors in the complex formation.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
J. Szejtli:Cyclodextrins and their Inclusion Complexes, Akademiai Kiado, Budapest (1982).
A. Nakajima:Spectrochim. Acta 39A, 913 (1983).
J. F. DeLuccia and L. J. Cline Love:Anal. Chem. 56, 2811 (1984).
S. Scypinski and L. J. Cline Love:Anal. Chem. 56, 322 (1984).
A. Nakajima:Bull. Chem. Soc. Jpn. 57, 1143 (1984).
G. Patonay, M. E. Rollie, and I. M. Warner:Anal. Chem. 57, 569 (1985).
G. Patonay, A. Shapira, P. Diamond, and I. M. Warner:J. Phys. Chem. 90, 1965 (1986).
H. E. Zimmerman, T. D. Goldman, T. K. Hirzel, and S. P. Schmidt:J. Org. Chem. 45, 3933 (1980).
K. Kalyanasundaram and J. K. Thomas:J. Am. Chem. Soc. 99, 2039 (1977).
G. Nelson, G. Patonay, and I. M. Warner: submitted toAnal. Chem.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Patonay, G., Fowler, K., Shapira, A. et al. Cyclodextrin complexes of polyaromatic hydrocarbons in the presence of aliphatic alcohols. Journal of Inclusion Phenomena 5, 717–723 (1987). https://doi.org/10.1007/BF00656591
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00656591