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Electrical properties of vanadium pentoxide doped with lithium and sodium in the α-phase range

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Abstract

The electrical conductivity and Seebeck coefficients have been measured from room temperature to 500° C for polycrystalline V2O5 and V2O5 doped with lithium and sodium in the α-phase range. The conductivity increases with doping and the energy of activation decreases. The Seebeck coefficient indicates that electrons are the majority carriers. The results have been discussed in terms of the two-level hopping model.

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References

  1. C. Wagner and K. Hauffe, Z. Electrochem. 44 (1938) 172.

    Google Scholar 

  2. K. Hauffe and E. G. Schlosser, ——ibid 61 (1957) 506.

    Google Scholar 

  3. C. G. B. Garret, J. Chem. Phys. 33 (1960) 966.

    Google Scholar 

  4. F. F. Wolkenstein, Adv. Catalysis 12 (1960) 189.

    Google Scholar 

  5. A. Hardy, J. Galy, A. Casalot and M. Pouchard, Bull. Soc. Chim. Fr. (1965) 1056.

  6. P. Hagenmuller, J. Galy, M. Pouchard and A. Casalot, Mater. Res. Bull. 1 (1966) 45.

    Google Scholar 

  7. A. D. Wadsley, Acta Cryst. 8 (1955) 695.

    Google Scholar 

  8. R. P. Ozerov, G. A. Gol'der and G. S. Zhdanov, Sov. Phys.-Cryst. 2 (1957) 221.

    Google Scholar 

  9. H. G. Bachmann and W. H. Barness, Z. Krist. 115 (1961) 215.

    Google Scholar 

  10. J. H. Perlstein and M. J. Sienko, J. Chem. Phys. 48 (1968) 174.

    Google Scholar 

  11. I. B. Patrina and V. A. Ioffe, Sov. Phys.-Solid State 6 (1965) 2581.

    Google Scholar 

  12. H. Clark and D. J. Berets, Adv. Catalysis 9 (1957) 204.

    Google Scholar 

  13. I. K. Bhatnagar, D. K. Chakrabarty and A. B. Biswas, Ind. J. Chem. 10 (1972) 1025.

    Google Scholar 

  14. A. Uhlir, Bell System. Tech. J. 34 (1955) 105.

    Google Scholar 

  15. F. M. Smits, ——ibid 37 (1958) 711.

    Google Scholar 

  16. A. A. Vinogradov and A. I. Shelykh, Sov. Phys.-Solid State 13 (1972) 2781.

    Google Scholar 

  17. V. A. Ioffe and I. B. Patrina, Phys. Stat. Sol. 40 (1970) 389.

    Google Scholar 

  18. A. R. Tourkey, Z. Hanafi and K. Al Zervel, Z. Phys. Chem. (Leipzig) 242 (1969) 218.

    Google Scholar 

  19. J. H. Perlstein, J. Solid State Chem. 3 (1971) 217.

    Google Scholar 

  20. J. Gendell, R. M. Cotts and M. J. Sienko, J. Chem. Phys. 37 (1962) 220.

    Google Scholar 

  21. D. S. Volzhenskii and M. V. Peshkovskii, Sov. Phys.-Solid State 11 (1969) 950.

    Google Scholar 

  22. T. Allersma, R. Hakim, T. N. Kennedy and J. D. Mackenzie, J. Chem. Phys. 46 (1967) 154.

    Google Scholar 

  23. A. Bystrom, K. A. Wichelmi and O. Brotzen, Acta. Chem. Scand. 4 (1950) 1119.

    Google Scholar 

  24. H. G. Bachmann, F. R. Ahmed and W. H. Barnes, Z. Krist. 115 (1961) 110.

    Google Scholar 

  25. M. Pouchard, A. Casalot, G. Villeneuve and P. Hagenmuller, Mat. Res. Bull. 2 (1967) 877.

    Google Scholar 

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Authors and Affiliations

  1. Chemistry Department, Indian Institute of Technology, 400 076, Powai, Bombay

    D. K. Chakrabarty, Dipak Guha & A. B. Biswas

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  1. D. K. Chakrabarty
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  2. Dipak Guha
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  3. A. B. Biswas
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Chakrabarty, D.K., Guha, D. & Biswas, A.B. Electrical properties of vanadium pentoxide doped with lithium and sodium in the α-phase range. J Mater Sci 11, 1347–1353 (1976). https://doi.org/10.1007/BF00545157

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  • DOI: https://doi.org/10.1007/BF00545157

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