Skip to main content
SpringerLink
Log in

ESR and Mössbauer studies of the precipitation process of various ferrites from silicate glasses

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

ESR and Mössbauer studies of the precipitation process of various ferrites from silicate glasses were made to characterize the precipitation mechanism. The changes in linewidth (ΔH 1/2) and effectiveg-value (g eff) in the ESR spectra of the precipitation process are well explained in terms of super-exchange interaction between magnetic ions and interparticle dipolar interaction between precipitated ferrites. The precipitation tendency of spinel type ferrites from silicate glasses was found to be in the following order: NiFe2O4≫CoFe2O4>Fe3O4≧ZnFe2O4, MnFe2O4. The above order coincided with the order of octahedral site preference energies of divalent transition metal ions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. R. R. Shaw andJ. H. Heasley,J. Amer. Ceram. Soc. 50 (1967) 297.

    Google Scholar 

  2. W. J. S. Blackburn andB. P. Tilley,J. Mater. Sci. 9 (1974) 1265.

    Google Scholar 

  3. B. T. Shirk andW. R. Buessem,J. Amer. Ceram. Soc. 53 (1970) 192.

    Google Scholar 

  4. M. O'horo andR. Steinitz,Mater. Res. Bull. 3 (1968) 117.

    Google Scholar 

  5. A. Prasad, D. Bahadur, R. M. Singru andD. Chakravorty,J. Mater. Sci. 17 (1982) 2687.

    Google Scholar 

  6. T. Komatsu, N. Soga andM. Kunugi,J. Appl. Phys. 50 (1979) 6469.

    Google Scholar 

  7. T. Komatsu andN. Soga,ibid. 51 (1980) 601.

    Google Scholar 

  8. Idem, ibid. 51 (1980) 5926.

    Google Scholar 

  9. D. W. Collins andL. N. Mulay,J. Amer. Ceram. Soc. 53 (1970) 74.

    Google Scholar 

  10. Y. Goto andK. Takahashi,J. Ceram. Assoc. Jpn. 80 (1972) 358.

    Google Scholar 

  11. T. Komatsu andN. Soga,J. Chem. Phys. 72 (1980) 1781.

    Google Scholar 

  12. Yu. D. Kruchinin andT. M. Pogodina,J. Appl. Chem. USSR, Consultants Bur. Tranl.45 (1972) 1500.

    Google Scholar 

  13. R. J. P. Williams,Nature 184 (1959) 44.

    Google Scholar 

  14. R. G. Burns andW. S. Fyfe,Chem. Geol. 1 (1966) 49.

    Google Scholar 

  15. C. D. Curtis,Geochim. Cosmochim. Acta 28 (1964) 389.

    Google Scholar 

  16. R. G. Burns andW. S. Fyfe,Science 144 (1964) 1001.

    Google Scholar 

  17. T. M. Seward,Chem. Geol. 7 (1971) 73.

    Google Scholar 

  18. J. D. Dunitz andL. E. Orgel,J. Phys. Chem. Solids 3 (1957) 318.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Materials Science and Technology, Technological University of Nagaoka, 949-54, Nagaoka, Japan

    T. Komatsu

  2. Department of Industrial Chemistry, Kyoto University, 606, Kyoto, Japan

    N. Soga

Authors
  1. T. Komatsu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. Soga
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Komatsu, T., Soga, N. ESR and Mössbauer studies of the precipitation process of various ferrites from silicate glasses. J Mater Sci 19, 2353–2360 (1984). https://doi.org/10.1007/BF01058111

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01058111

Keywords

Search

Navigation