Abstract
The numerical solution of the one-dimensional nonlinear diffusion equation with a negative diffusion coefficient (up-hill diffusion) by a five-point approximation central difference scheme is considered. The stability criteria are discussed in detail and a numerical solution is provided for a specific case in which the time evolution of a periodic composition wave is presented with growth eventually leading to a stationary configuration. A critical comparison of the numerical solution with existing analytical solutions is shown. This leads to a simple semi-empirical growth law for studying the kinetics of spinodal decomposition in alloys.
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Tsakalakos, T., Dugan, M.P. Nonlinear diffusion in spinodal decomposition: a numerical solution. J Mater Sci 20, 1301–1309 (1985). https://doi.org/10.1007/BF01026326
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DOI: https://doi.org/10.1007/BF01026326