Skip to main content
Log in

Nonlinear diffusion in spinodal decomposition: a numerical solution

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

The numerical solution of the one-dimensional nonlinear diffusion equation with a negative diffusion coefficient (up-hill diffusion) by a five-point approximation central difference scheme is considered. The stability criteria are discussed in detail and a numerical solution is provided for a specific case in which the time evolution of a periodic composition wave is presented with growth eventually leading to a stationary configuration. A critical comparison of the numerical solution with existing analytical solutions is shown. This leads to a simple semi-empirical growth law for studying the kinetics of spinodal decomposition in alloys.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. J. E. Hilliard, “Phase Transformations”, edited by H. I. Aaronson, (American Society of Metals, Metals Park, Ohio, 1970), pp. 497–556.

    Google Scholar 

  2. B. Ditchek andL. H. Schwartz,Ann. Rev. Mater. Sci. 9 (1979) 219.

    Google Scholar 

  3. J. W. Cahn,Acta Metall. 9 (1961) 795.

    Google Scholar 

  4. Idem, ibid. 10 (1962) 179.

    Google Scholar 

  5. Idem, ibid. 14 (1966) 1685.

    Google Scholar 

  6. J. S. Langer,Ann. Phys. 65 (1971) 53.

    Google Scholar 

  7. T. Tsakalakos, PhD thesis, Northwestern University Evanston, Illinois (1977).

    Google Scholar 

  8. J. W. Cahn andJ. E. Hilliard,J. Chem. Phys. 28 (1958) 25.

    Google Scholar 

  9. I. S. Gradshteyn andI. M. Ryzhik, “Table of Integrals, Series and Products” (Academic Press, New York, 1965).

    Google Scholar 

  10. J. L. Siemieniuch andI. Gladwell,Int. J. Num. Meth. Engng. 12 (1978) 899.

    Google Scholar 

  11. D. F. Griffiths, I. Christie andA. R. Mitchell,ibid. 15 (1980) 1075.

    Google Scholar 

  12. C. F. Gerald, “Applied Numerical Analysis”, (Addison-Wesley, Reading, Massachusetts, 1978) pp. 392–416.

    Google Scholar 

  13. J. H. Wilkinson, “Algebraic Eigenvalue Problem” (Oxford University Press, Oxford 1965).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tsakalakos, T., Dugan, M.P. Nonlinear diffusion in spinodal decomposition: a numerical solution. J Mater Sci 20, 1301–1309 (1985). https://doi.org/10.1007/BF01026326

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01026326

Keywords

Navigation