Skip to main content
Log in

On the optical properties of Mn/SiO and SiO thin films

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

The ultraviolet, visible and infrared properties of unannealed and annealed amorphous Mn/SiO cermet thin films (300 to 1000 nm thick) prepared by vacuum evaporation at 5.0×10−4 Pa are investigated. The ultraviolet and visible results are analysed assuming optical absorption by indirect transitions. A systematic reduction of the optical energy gap and an increase in the width of the band-tail region is observed with increasing metallic content. The effects of the ratio deposition rate/residual pressure and substrate temperature on the optical properties of SiO x (1<x<2) thin films are also investigated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. J. Tauc, “Amorphous and Liquid Semiconductors” (Plenum Press, London, 1974) p. 159.

    Google Scholar 

  2. J. Tauc, R. Grigorovici andA. Vancu,Phys. Status Solidi 15 (1966) 627.

    Google Scholar 

  3. E. A. Davis andN. F. Mott,Phil. Mag. 22 (1970) 903.

    Google Scholar 

  4. N. F. Mott andE. A. Davis, “Electronic Processes In Non-crystalline Materials” (Clarendon Press, Oxford, 1979) pp. 291, 497.

    Google Scholar 

  5. G. R. Moridi andC. A. Hogarth, Proceedings 7th International Conference on Amorphous and Liquid Semiconductors (Edinburgh) (1977) edited by W. E. Spear (Centre for Industrial Consultancy, Edinburgh) p. 688.

    Google Scholar 

  6. C. A. Hogarth andM. Y. Nadeem,Phys. Status Solidi (2) 68 (1981) K181.

    Google Scholar 

  7. S. K. J. Al-Ani, K. Arshak andC. A. Hogarth,J. Mater. Sci. 19 (1984) 1737.

    Google Scholar 

  8. F. Urbach,Phys. Rev. 92 (1953) 1324.

    Google Scholar 

  9. J. E. Morris andT. J. Coutts,Thin Solid Films 47 (1977) 1.

    Google Scholar 

  10. Z. H. Meiksin,Phys. Thin Films 8 (1975) 99.

    Google Scholar 

  11. B. Abeles, Ping Sheng, M. D. Coutts andY. Arle,Adv. Phys. 24 (1976) 407.

    Google Scholar 

  12. A. A. Milgram andC. S. Lu,J. Appl. Phys. 39 (1968) 4219.

    Google Scholar 

  13. R. Glang, R. A. Holmwood andS. R. Herd,J. Vac. Sci. Technol. 4 (1967) 163.

    Google Scholar 

  14. J. E. Morris,Thin Solid Films 11 (1972) 299.

    Google Scholar 

  15. J. K. Pollard, R. L. Bell andG. G. Bloodsworth,J. Vac. Sci. Technol. 6 (1969) 702.

    Google Scholar 

  16. E. M. Castro andJ. Beynon,Thin Solid Films 66 (1980) L19.

    Google Scholar 

  17. Idem, ibid. 66 (1980) L21.

    Google Scholar 

  18. Idem, ibid. 69 (1980) L21.

    Google Scholar 

  19. Idem, ibid. 69 (1980) L43.

    Google Scholar 

  20. T. S. Moss, G. J. Burrell andB. Ellis, “Semiconductor Opto-electronics” (Butterworth, 1973) 18.

  21. J. D. Dow andD. Redfield,Phys. Rev. B5 (1972) 594.

    Google Scholar 

  22. J. Tauc, “The Optical Properties of Solida”, edited by F. Abeles (North Holland, Amsterdam, 1970) p. 277.

    Google Scholar 

  23. A. R. Sarkar, unpublished results.

  24. A. P. Bradford, G. Hass, M. McFarland andE. Ritter,Thin Solid Films 42 (1977) 361.

    Google Scholar 

  25. H. R. Philipp,J. Phys. Chem. Solids 32 (1971) 1935.

    Google Scholar 

  26. A. L. Shabalov andM. S. Feldman,Thin Solid Films 110 (1983) 215.

    Google Scholar 

  27. E. Ritter,Opt. Acta 9 (1962) 197.

    Google Scholar 

  28. M. N. Khan andE. E. Khawaja,Phys. Status Solidi (a) 74 (1982) 273.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Al-Ani, S.K.J., Sarkar, M.A.R., Beynon, J. et al. On the optical properties of Mn/SiO and SiO thin films. J Mater Sci 20, 1637–1644 (1985). https://doi.org/10.1007/BF00555267

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00555267

Keywords

Navigation