Abstract
The electrical conductivity, thermoelectric power and dielectric constant of Eu2Ti2O7 single crystal have been studied in the temperature range 300–1000 K. Eu2Ti2O7 is found to be a n-type semiconductor with energy band gap of 2.5 eV. The compound exhibits an extrinsic nature upto 700 K and intrinsic nature above 700 K. Thermoelectric power decreases with temperature in the region 300–700 K whereas it increases with temperature in the region 700–1000 K. Dielectric constant increases with temperature in the entire temperature range studied with a discontinuity atT ∼ 700 K.
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M. P. Van Dijk, J. H. H. Termaat, G. Roelofs, H. Bosch, G. M. H. Van De Velde, P. J. Gellings andA. J. Burggraaf,Mat. Res. Bull. 19 (1984) 1149.
M. Faucher andP. Caro,J. Solid State Chem. 12 (1975) 1.
B. M. Wanklyn,J. Mater. Sci. 7 (1972) 813.
Y. P. Yadava andR. A. Singh,Mater. Chem. Phys. 17 (1987) 259.
T. C. Hermann andJ. M. Honing, in “Thermoelectric power and Thermomagnetic Effects and Applications” (McGraw-Hill, New York, 1976) p. 142.
I. K. Naik andT. Y. Tien,J. Phys. Chem. Solids 39 (1978) 311.
A. J. Dekker, in “Solid State Physics” (MacMillan, London, 1964) p. 305.
B. Conqulin andA. Blandin,Adv. Phys. 17 (1968) 281.
C. E. T. Goncalves Da Silva andL. M. Falicov,J. Phys. C: Solid State Phys. 5 (1972) 63.
Y. A. Rocher,Adv. Phys. 11 (1962) 233.
R. Ramirez andL. M. Falicov,Phys. Rev. 13 (1971) 2425.
J. M. Ziman, in “Principles of the theory of solids” (Cambridge University Press, UK, 1964) p. 179.
C. Kittel, in “Introduction to Solid State Physics” (Wiley, New York, 1971) p. 361.
H. Frohlich,Adv. Phys. 3 (1954) 325.
G. R. Allcock,ibid. 5 (1956) 412.
J. Appel, in “Solid State Physics” (Academic Press, New York, 1968) p. 193.
O. G. Palanna, A. L. Shashi Mohan, A. B. Biswas,Proc. Indian Acad. Sci. 86A (1977) 455.
J. P. Suchet, in “Electrical Conduction in Solid Materials” (Pergamon Press, Oxford, 1975) p. 47.
C. P. Smyth, in “Dielectric Behaviour and Structure” (McGraw-Hill, New York, 1955) p. 132.
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Pandit, A.K., Ansari, T.H., Singh, R.S. et al. Electrical transport properties of Eu2Ti2O7 single crystal. J Mater Sci 27, 4080–4084 (1992). https://doi.org/10.1007/BF01105108
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DOI: https://doi.org/10.1007/BF01105108