Skip to main content
Log in

Studies on polypropylene composites filled with talc particles

Part I Mechanical properties

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

Tensile and impact properties of talc-filled isotactic polypropylene composites are investigated at 0–60 wt% filler contents. Tensile modulus registered an increase whereas tensile yield strength and strain-at-break decreased with increasing filler content. Mechanical restraint imposed by the talc particles on the molecular mobility or deformability of polypropylene explained the increase in modulus and decrease in strain-at-break while decrease in tensile yield strength was attributed to decreased crystallinity and formation of stress concentration points around the filler particles. Izod impact strength decreased with increased talc content. Surface modification of talc with a titanate coupling agent LICA 38 enhanced the filler-polymer interaction, further modifying the composite properties consequent upon significant decrease in the stress concentration. Scanning electron microscopic studies revealed better dispersion of surface-modified filler particles in the polymer matrix.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. M. E. J. Dekkers andD. Heikens,J. Appl. Polym. Sci. 30 (1985) 2389.

    Google Scholar 

  2. S. Cacoutis, R. T. Woodhams andP. G. K. Van De Poll,Polym. Compos. 9 (1983) 51.

    Google Scholar 

  3. J. E. Stamhuis,ibid. 9 (1988) 72.

    Google Scholar 

  4. H. Katz andJ. V. Milewski (eds), “Handbook of Fillers and Reinforcement for Plastics” (Van Nostrand, Reinhold, New York, 1978).

    Google Scholar 

  5. J. A. Brydson, “Plastics Materials”, 5th Edn (Newnes-Butterworths, London, 1989).

    Google Scholar 

  6. S. J. Monte andG. Sugerman, “Ken-React Reference Manual” (Bulletin No. KR-1084L, 1985).

  7. O. Laguna, J. P. Vigo andE. P. Collar,Rev. Plast. Mod. 53 (1987) 367; (C.F.C.A. 106 (24), 197237u 1987).

    Google Scholar 

  8. B. Serafimov,Plast. Kautsch. 29 (1982) 598 (C.F.C.A. 98 (8), 54975p 1982).

    Google Scholar 

  9. S. N. Maiti andP. K. Mahapatro,Int. J. Polym. Mater. 13 (1990) 1.

    Google Scholar 

  10. L. Czarnecki andJ. L. White,J. Appl. Polym. Sci. 25 (1980) 1217.

    Google Scholar 

  11. J. A. Manson andL. H. Sperling, “Polymer Blends and Composites” (Plenum, New York, 1976) Ch. 12.

    Google Scholar 

  12. C. D. Han, T. Van Den Weghe, P. Shete andJ. R. Haw,Polym. Engng Sci. 21 (1981) 196.

    Google Scholar 

  13. S. N. Maiti andP. K. Mahapatro,Polym. Plast. Technol. Engng,30(5&6) (1991) 559.

    Google Scholar 

  14. N. K. Jha, A. C. Misra, N. K. Tiwari andP. Bajaj,Polym. Engng Sci. 25 (1985) 434.

    Google Scholar 

  15. J. A. Ashman andA. Mudrak, US Pat. 41000 075 (1978)

  16. Harshaw Chemical Co. (C.F.C.A.90, 55741f 1979).

    Google Scholar 

  17. E. H. Kerner,Proc. Phys. Soc. 69B (1969) 808.

    Google Scholar 

  18. L. E. Nielsen, “Mechanical Properties of Polymers and Composites” (Marcel-Dekker, New York, 1974).

    Google Scholar 

  19. V. Dolakova-Svehlova,J. Macromol. Sci. Phys. B 21 (1982) 231.

    Google Scholar 

  20. E. Guth andH. Smallwood,J. Appl. Phys. 15 (1944) 758.

    Google Scholar 

  21. F. Ramsteiner andR. Theyson,Composites 15 (1984) 121.

    Google Scholar 

  22. F. F. Lange, in “Fracture and Fatigue”, “Composite Materials”, Vol. 5, edited by L. J. Broutman (Academic Press, New York, 1974) p. 2.

    Google Scholar 

  23. G. W. Brassel andK. B. Wischmann,J. Mater. Sci. 9 (1974) 307.

    Google Scholar 

  24. L. J. Broutman andR. H. Krock, “Modern Composite Materials” (Addison-Wiley, Reading, MA 1967).

    Google Scholar 

  25. A. Baumgarter andM. Muthukumar,J. Chem. Phys. 87 (1987) 3082.

    Google Scholar 

  26. A. K. Gupta, V. B. Gupta, R. H. Peters, W. G. Harland andJ. P. Berry,J. Appl. Polym. Sci. 27 (1982) 4669.

    Google Scholar 

  27. K. K. Sharma, MTech dissertation, IIT, New Delhi (1987).

    Google Scholar 

  28. S. N. Maiti andP. K. Mahapatro,J. Appl. Polym. Sci.,42 (1991) 3101.

    Google Scholar 

  29. C. D. Han, C. Sandford andH. J. Yoo,Polym. Engng Sci. 18 (1978) 849.

    Google Scholar 

  30. K. Mitsuishi, S. Kodama andH. Kawasaki,ibid. 25 (1985) 1069.

    Google Scholar 

  31. A. K. Gupta andS. N. Purwar,J. Appl. Polym. Sci. 22 (1984) 3513.

    Google Scholar 

  32. T. Kunori andP. H. Geil,J. Macromol. Sci. Phys. B 18 (1980) 135.

    Google Scholar 

  33. M. R. Piggott andJ. Leidner,J. Appl. Polym. Sci. 18 (1974) 1619.

    Google Scholar 

  34. L. E. Nielsen,ibid. 10 (1966) 97.

    Google Scholar 

  35. L. Nicolais andM. Narkis,Polym. Engng Sci. 11 (1971) 194.

    Google Scholar 

  36. L. Nicolais andL. Nicodemo,Int. J. Polym. Mater. 4 (1974) 229.

    Google Scholar 

  37. L. Nicodemo andL. Nicolais,J. Mater. Sci. Lett. 2 (1983) 201.

    Google Scholar 

  38. S. N. Maiti andR. Jeyakumar,J. Polym. Mater. 7 (1990) 29.

    Google Scholar 

  39. E. M. Passmore, R. M. Spriggs andT. Vasilos,J. Amer. Ceram. Soc. 48 (1965) 1.

    Google Scholar 

  40. L. E. Nielsen,J. Compos. Mater,1 (1967) 100.

    Google Scholar 

  41. S. Sahu andL. J. Broutman,Polym. Engng Sci. 12 (1972) 91.

    Google Scholar 

  42. G. W. Brassel andK. B. Wischmann, SPE Regional Technical Conference on Advances in Reinforced Thermoplastics, Paper 1 (El Segundo, CA 1972).

    Google Scholar 

  43. O. Ishai andL. J. Cohen,J. Compos. Mater. 2 (1968) 302.

    Google Scholar 

  44. L. Nicolais andL. Nicodemo,Polym. Engng Sci. 7 (1967) 1.

    Google Scholar 

  45. S. N. Maiti andR. Subbarao,Int. J. Polym. Mater.,15 (1991) 1.

    Google Scholar 

  46. Y. N. Sharma, S. F. Xavier andJ. S. Anand, in “Proceedings of the Seminar on Matrix Resins for Composites”, DST, New Delhi (1986) p. 223.

    Google Scholar 

  47. M. S. Boira andC. E. Chaffey,Polym. Engng Sci. 10 (1977) 715.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Maiti, S.N., Sharma, K.K. Studies on polypropylene composites filled with talc particles. J Mater Sci 27, 4605–4613 (1992). https://doi.org/10.1007/BF01165994

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01165994

Keywords

Navigation