Abstract
Pressureless sintering of ultrafine SiC powder containing a large amount of free Si was carried out with the aid of boron. Epitaxial growth of secondary particles was observed by scanning electron microscopy (SEM) on some hexagonal-shaped surfaces of β-SiC cube-octahedra. The other hexagonal-shaped surfaces were seen to be entirely smooth. The two-fold symmetry of the [100] axes for the appearance of secondary particles certainly reflects the polarity of β-SiC. When the sintering was repeated again, coalescence growth of secondary particles was remarkable on the former surfaces and layered growth was predominant on the latter surfaces.
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Ando, Y., Iwanaga, H. Observation of secondary particles grown on crystal surfaces of silicon carbide. JOURNAL OF MATERIAL SCIENCE 28, 5722–5724 (1993). https://doi.org/10.1007/BF00365172
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DOI: https://doi.org/10.1007/BF00365172