Abstract
The influence of two types of a styrene–ethylene/butylene–styrene (SEBS) triblock copolymer, one as received and the other functionalized with maleic anhydride, on model interfaces of high-density polyethylene (HDPE) and isotactic polypropylene (iPP) was investigated. Using a special preparation technique, it was possible to prevent gross interdiffusion at the interface and to attribute the problem to an adhesion-dominated phenomenon. The weak mechanical strength of the unmodified interfaces, iPP/iPP and HDPE/HDPE, was greatly improved by the triblock copolymer as was shown by the results of a T-peel test. The morphologies of the peeled surfaces of the modified and unmodified interfaces were analysed with light microscopy. The morphology of both model interface systems show differences, thus revealing different processes at the interfaces and thus different interactions of SEBS with iPP and HDPE and a different influence of the functionalization. The best results were achieved using the functionalized SEBS; the influence of functionalization was greater in the HDPE system. The results are in good agreement with a model proposed by the present authors elsewhere for the concentration-dependent role of SEBS in binary iPP/SEBS and ternary iPP/PE/SEBS blends.
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References
D. R. Paul and S. Newman, “Polymer blends”, Vol. 1 (Academic Press, New York, 1978).
Idem., “Polymer blends”, Vol. 2 (Academic Press, New York 1978).
L. A. Utracki, “Polymer alloys and blends: thermodynamics and rheology” (Hanser, New York, 1990).
L. A. Utracki and R. A. Weiss, “Multiphase polymers: blends and ionomer”, ACS Symposium Series 395 (American Chemical Society, Washington, DC, 1989).
J. Karger-Kocsis, “Polypropylene: structure, blends and composites”, Vol. 2 (Chapman & Hall, London, 1995).
A. Lovinger and M. Wiliams, J. Appl. Polym. Sci. 25 (1980) 1703.
D. W. Bartlett, J. W. Barlow and D. R. Paul, ibid. 27 (1982) 351.
O. F. Noel and J. F. Carley, Polym. Engng Sci. 15 (1975) 117.
J. W. Teh, J. Appl. Polym. Sci. 28 (1983) 605.
L. A. Utracki, in “Multiphase polymers: blends and ionomers”, ACS Symposium Series 395, edited by A. Utracki and R. A. Weiss (American Chemical Society, Washington, DC, 1989) Ch. 7.
R. Fayt, R. Jerome and P. Teyssie, J. Polym. Sci., Polym. Phys. Edn 27 (1989) 775.
Idem., J. Polym. Sci., Polym. Lett. Edn 19 (1981) 79.
A. P. Plochocki, S. S. Dagli and R. D. Andrews, Polym. Engng Sci. 30 (1990) 741.
D. R. Paul, in “Polymer blends”, Vol. 2, edited by D. R. Paul and S. Newman (Academic Press, New York, 1978) Ch. 12.
M. Maglio and R. Palumbo, in Proceedings of the Second Polish—Italian Joint Seminar on Multicomponent Polymeric Systems, Lodz, September, 1982, edited by M. Kryszewski, A. Galeski and E. Martuscelli (Plenum, New York, 1984).
R. Fayt, R. Jerome and P. Teyssie, J. Polym. Sci., Polym. Phys. Edn 19 (1981) 1269.
R. Jerome and P. Teyssie, J. Polym. Sci., Polym. Phys. Edn Idem., ibid. 20 (1982) 2209.
Idem., Makromol. Chem. 187 (1986) 837.
G. H. Michler, “Kunststoff-Mikromechanik: Morphologie, Deformations-und Bruchmechanismen” (Carl Hanser, München, 1992).
J. J. Elmendorp, PhD thesis, TH Delft (1986).
V. Flaris, PhD thesis, Melbourne University, Melbourne (1993).
A. K. Gupta and S. N. Purwar, J. Appl. Polym. Sci. 30 (1985) 1799.
K. R. Srinivasan and A. K. Gupta, ibid. 53 (1994) 1.
M. C. Schwarz, J. W. Barlow and D. R. Paul, ibid. 37 (1989) 403.
D. W. Bartlett, D. R. Paul and J. W. Barlow, Mod. Plastics 58 (1981) 60.
V. Flaris, M. D. Zipper, G. P. Simon and A. J. Hill, Polym. Engng Sci. 39 (1993) 125.
D. R. Paul, in “Thermoplastic elastomers: a comprehensive review”, edited by N. R. Legge, G. Holden and H. E. Schroeder (Hanser, New York, 1987) Ch. 12/6.
A. L. Bull and G. Holden, J. Elastomers Plastics 9 (1977) 281.
T. D. Traugott, J. W. Barlow and D. R. Paul, J. Appl. Polym. Sci. 28 (1983) 2947.
U. Plawky, M. Schlabs and W. Wenig, ibid. 59 (1996) 1891.
U. Plawky and W. Wenig, in Proceedings of the 13th IUPAC Conference on Chemical Thermodynamics, Clermont-Ferrand, 17–22 July (Soc. Chim. Français, 1994) p. 266.
Idem., in Proceedings of the EPS Conference on Macromolecular Physics, Vol. 18C, Eindhoven, 4–7 July (1994).
Idem., Macromol. Symp. 102 (1990) 183.
W. P. Gergen, R. G. Lutz and S. Davison, in “Thermoplastic elastomers: a comprehensive review, edited by N. R. Legge, G. Holden and H. E. Schroeder (Hanser, New York, 1987) Ch. 14.
R. P. Wool, in “Polypropylene”, Vol. 1, “Structure and morphology”, edited by J. Karger-Kocsis (Chapman & Hall, London, 1995) Ch. 8.
B.-L. Yuan and R. P. Wool, Polym. Engng Sci. 30 (1990) 1454.
G. Menning, in “Polypropylene”, Vol. 1, “Structure and morphology”, edited by J. Karger-Kocsis (Chapman & Hall, London, 1995) Ch. 7
G. Lin, W. Wenig and J. Petermann, J. Mater Sci. (1996) submitted.
Anon., “Winkelschälversuch” DIN 53282 (Beuth, Berlin, 1979).
J. D. Keitz, J. W. Barlow and D. R. Paul, J. Appl. Polym. Sci. 29 (1984) 3131.
G. Hagenbeck, Diploma thesis, University of Duisburg, Duisburg (1982).
J. Petermann and R. M. Gohil, J. Mater. Sci. 14 (1979) 2260.
W. P. Gergen, “Uniqueness of hydrogenated block copolymers for elastomer application” (Shell Development Company, Houston, TX, 1989).
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Plawky, U., Wenig, W. Improvement in the mechanical strength of asymmetric polyolefin model interfaces. Journal of Materials Science 33, 1611–1618 (1998). https://doi.org/10.1023/A:1017524106188
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DOI: https://doi.org/10.1023/A:1017524106188