Abstract
Metal layer was deposited by the reduction of NiCl2 and CoCl2 in polyacrylonitrile film after applying an external magnetic field in directions parallel and perpendicular to the surface of the film; the magnetic properties of the metal-deposited film were investigated. When the parallel magnetic field was applied, the values of coercivity (Hc), remanent flux density (Br) and maximum flux density (Bs) increased regardless of the composition of the metal ions, compared with the case without the application of the magnetic field. From the scanning electron micrographs and X-ray diffraction analyses, it was shown that the growth of crystalline orientation in the deposited metals was enhanced by applying a parallel magnetic field.
Similar content being viewed by others
References
T. Yosomiya, H. Ono and R. Yosomiya, Angew. Makromol. Chem., 197, 49 (1992).
M. Shibata, R. Yosomiya and T. Yosomiya, Angew. Makromol. Chem., 253, 183 (1997).
T. Osaka, N. Kasai, I. Koiwa, F. Goto and Y. Suganuma, J. Electrochem. Soc., 130, 568 (1983).
I. Koiwa, M. Toda and T. Osaka, J. Electrochem. Soc., 133,597 (1986).
E. L. Nicholson and M. R. Khan, J. Electrochem. Soc., 133, 2342 (1986).
S. A. Armyanor and G. S. Sotirova, J. Electrochem. Soc., 136, 1575 (1989).
Y. Moradzaheh, J. Electrochem. Soc., 112, 891 (1965).
J. Hokkyo, T. Onoue, N. Miyamoto, T. Homma and T. Osaka, J. Magn. Soc. Jpn., 21, 525 (1997).
T. Yosomiya, Y. Sato and R. Yosomiya, Angew. Makromol. Chem., 206, 209 (1993).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Shibata, M., Beniya, H., Yosomiya, R. et al. Magnetic properties of metal layer deposited by reduction of metal ions contained in polymer with applying magnetic field. J Polym Res 7, 57–61 (2000). https://doi.org/10.1007/s10965-006-0104-1
Received:
Revised:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/s10965-006-0104-1