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Phase Transition in Trans and Cis-1,2-Cyclohexanediol Studied by Infrared Spectroscopy

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Abstract

The study of trans- and cis-1,2-cyclohexanediol by infrared spectroscopy was performed. The variation of the maximum frequency and of the bandwidth of the OH stretching vibration give evidence of the role played by hydrogen bonding in the solid and liquid phases of both isomers and allows to follow the phase transitions. A solid rotator phase is shown for the cis compound.

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Authors
  1. M. L. P. Leitão
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  2. C. M. R. Nobre
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  3. J. L. Jesus
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  4. J. S. Redinha
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Leitão, M.L.P., Nobre, C.M.R., Jesus, J.L. et al. Phase Transition in Trans and Cis-1,2-Cyclohexanediol Studied by Infrared Spectroscopy. Journal of Thermal Analysis and Calorimetry 57, 111–118 (1999). https://doi.org/10.1023/A:1010124928198

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  • DOI: https://doi.org/10.1023/A:1010124928198

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