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Kinetic and Thermodynamic Studies of Facial and Meridional uns-cis-[Co(eddp)gly] Complexes

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Abstract

Thermal properties of facial and meridional uns-cis-[Co(eddp)gly]0.5H2O complexes were investigated by means of DSC and TG techniques. It wasshown that the processes of thermal decomposition of these complexes are multi-stepdegradation processes, which can also be well separated into individual steps, depending onthe molecular symmetry. Thus, the process of thermal degradation of the meridional isomerof the above complex consists of 4 well-separated steps in the temperature interval from 100to 500°C. The corresponding kinetic and thermodynamic parameters of this process weredetermined, and a possible mechanism is discussed.

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Authors and Affiliations

  1. Faculty of Physical Chemistry, University of Belgrade, P.O. Box 173, 11000, Belgrade, Yugoslavia

    N. Petranović & D. Minić

  2. Faculty of Chemistry, University of Belgrade, P.O. Box 158, 11000, Belgrade, Yugoslavia

    T. J. Sabo & D. Doković

Authors
  1. N. Petranović
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  2. D. Minić
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  3. T. J. Sabo
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  4. D. Doković
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Petranović, N., Minić, D., Sabo, T.J. et al. Kinetic and Thermodynamic Studies of Facial and Meridional uns-cis-[Co(eddp)gly] Complexes. Journal of Thermal Analysis and Calorimetry 59, 807–814 (2000). https://doi.org/10.1023/A:1010157821694

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  • DOI: https://doi.org/10.1023/A:1010157821694

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