Abstract
The conversion, the reduced rate of conversion dC/dΘ andΘ at the peak of derivative thermoanalytical curve of diffusion are estimated theoretically, solving the theoretical equation with an electronic digital computer. These values for chemical reactions including random degradation of polymers are also estimated and compared with those of diffusion. The conversion at the peak is utilized to elucidate preliminarily the mechanism of the process.
References
T. Ozawa, J. Thermal Anal., 5 (1973) 563.
T. Ozawa, ibid., 2 (1970) 301.
C. D. Doyle, Nature, 207 (1965) 290; J. Appl. Polymer Sci., 6 (1962) 639.
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Ozawa, T. The peak of the derivative thermoanalytical curve of diffusion. Journal of Thermal Analysis 6, 401–403 (1974). https://doi.org/10.1007/BF01950071
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DOI: https://doi.org/10.1007/BF01950071