Skip to main content
Log in

On the reaction of aluminosilicates with aqueous solutions of NaOH and KF

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

Neutralization of H-mordenite with NaOH follows diffusion kinetics with the diffusion of sodium cations into the mordenite as rate-determining step; neutralization curves are determined by the H3O+→Na+ ion exchange isotherm. With KF solutions, all aluminium can be extracted from the lattice of NaY-zeolite.

Abstract

Нейтрализация Н-морденита NaOH протекает по диффузионной кинетике, где ступенью, лимитирующей скорость процесса, является диффузия натриевых ионов в морденит. Кривые нейтрализации были определены с помощью ионообменной изотермы H3O+→Na+. С помощью раствора KF весь алюминий может быть экстрагирован из решетки цеолита NaY.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. H.P. Boehm: Adv. Catal. Rel. Subj.,16, 179 (1966).

    Google Scholar 

  2. A.L. Hensley, J.E. Borney: J. Phys. Chem.,62, 1560 (1958).

    Google Scholar 

  3. D.W. Breck, G.W. Skeels: Proc. Sixth Intern. Congr. on Catalysis, p. 645. The Chemical Society, London 1976.

    Google Scholar 

  4. G. Kühl: Molecular Sieves II-ASC-Symp. Ser. 40, p. 96. ACS, Washington D.c. 1977.

    Google Scholar 

  5. F. Wolf, C. Golz, K. Pilchowski: Z. phys. Chem.,257, 1148 (1976).

    Google Scholar 

  6. A.V. Rao, L.V. Rees: Trans. Faraday Soc.,62 2103, 2505 (1966).

    Google Scholar 

  7. K. Schwabe: Electrochim. Acta,12, 67 (1967); A. Ferse, E. Ferse: Z. Chemie,6, 241 (1966).

    Google Scholar 

  8. R.M. Barrer, J. Klinowski: Trans. Faraday Soc.,71, 690 (1975).

    Google Scholar 

  9. G.T. Kerr, A.W. Chester, D.H. Olson: Proc. Symposium on Zeolites, Szeged, Hungary, p. 169, 1978.

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bremer, H., Miklósy, E., Papp, J. et al. On the reaction of aluminosilicates with aqueous solutions of NaOH and KF. React Kinet Catal Lett 11, 45–50 (1979). https://doi.org/10.1007/BF02098332

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02098332

Keywords

Navigation