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Effect of radial distribution functions and poisson reparatition of reactants on the analysis of reactions involving long distance energy transfer

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Abstract

Starting from a uniform distribution and knowing the space dependent rate constant, it is possible to express the fluorescence quenching effect. In the case of long distance energy transfer (Forster), we show that the introduction of radial distribution functions and of non-uniform repartition of quenchers has only small effects on the kinetics of such reactions.

Abstract

Исходя из одинакового распределения и при знании объемной зависимости константы скорости можно выразить эффект тушения флуоресценции. В случае передачи энергии на длинные расстояния (Forster) было показано, что введение функции радиального распределения и неодинакового повторного участия тушителей приводит лишь к незначительным эффектам на кинетику таких реакций.

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Bouchy, A., Andre, J.C., Baros, F. et al. Effect of radial distribution functions and poisson reparatition of reactants on the analysis of reactions involving long distance energy transfer. React Kinet Catal Lett 39, 199–205 (1989). https://doi.org/10.1007/BF02061877

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  • DOI: https://doi.org/10.1007/BF02061877

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