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On the generation mechanism of aromatic cation-radicals under adsorption on zeolites

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Abstract

Nonempirical quantum-chemical calculations suggest a molecular model for oxygen adsorption on Lewis acid sites of zeolites. This adsorption complex is assumed to be capable of acting as an electron acceptor in the generation of benzene cation-radicals.

Abstract

На основе неэмпирических квантовохимических расчетов предложена молекулярная модель адсорбции кислорода на льюисовском кислотном центре цеолита. Сделано предположение о том, что такой адсорбционный комплекс способен выступать в качестве акцептора электрона в процессе образования катион-радикалов бензола.

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Authors and Affiliations

  1. Institute of Catalysis, 630090, Novosibirsk, Russia

    I. V. Yudanov, I. I. Zakharov & G. M. Zhidomirov

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  1. I. V. Yudanov
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  2. I. I. Zakharov
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  3. G. M. Zhidomirov
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Yudanov, I.V., Zakharov, I.I. & Zhidomirov, G.M. On the generation mechanism of aromatic cation-radicals under adsorption on zeolites. React Kinet Catal Lett 48, 411–417 (1992). https://doi.org/10.1007/BF02162689

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  • DOI: https://doi.org/10.1007/BF02162689

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