Summary
Cationic rhodium(I) complexes of the type [Rh(diolefin)(L-L)]ClO4 and [Rh(diolefin)L2]ClO4, (diolefin = 1,5-cyclooctadiene, 2,5-norbornadiene and tetrafluorobenzobarrelene; L-L = 2,2′-biimidazole, 2,2′-bibenzimidazole; L = pyrazole or imidazoles) are described. [Rh(CO)2(L-L)]-C1O4 complexes, which can be obtained by reaction of cyclooctadiene derivatives with CO, react with P-donor ligands in equimolar ratios to yield [Rh(CO)(P-donor)(L-L)]ClO4 monocarbonyl derivatives. The catalytic activity of some of these complexes is considered.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
M. Green, T. A. Kuc and S. H. Taylor,J. Chem. Soc. Chem. Commun., 1553 (1970).
G. Zassinovich, G. Mestroni and A. Camus,J. Mol. Catal., 2, 63 (1977).
G. Mestroni, G. Zassinovich and A. Camus,J. Organometal. Chem., 140, 63 (1977).
R. Usón, L. A. Oro, M. A. Garralda, M. C. Claver and P. Lahuerta,Transition Met. Chem., 4, 55 (1979).
R. Usón, L. A. Oro, J. Artigas and R. Sariego,J. Organometal. Chem., 179, 65 (1979).
G. Zassinovich, G. Mestroni and A. Camus,J. Organometal. Chem., 91, 379 (1975).
R. H. Crabtree, A. Gautier, G. Giordano and T. Khan,J. Organometal. Chem., 141, 113 (1977).
R. R. Schrock and J. A. Osborn,J. Am. Chem. Soc. 93, 3089 (1971).
J. Reedijk,Rec. Trav. Chim., 88, 1451 (1969).
J. Reedijk,Inorg. Chim. Acta, 3, 517 (1969).
R. Usón, L. A. Oro, J. A. Cuchi and M. A. Garralda,J. Organometal. Chem., 116, C35 (1976).
B. R. James, R. H. Morris and K. J. Reimer,Can. J. Chem., 55, 2353 (1977).
R. Ugo, G. La Monica, S. Cenini and F. Bonati,J. Organometal. Chem., 11, 159 (1968).
P.W. DeHaven and V. L. Goedken,Inorg. Chem., 18, 827 (1979).
C. A. Tolman,Chem. Rev., 77, 313 (1977).
R. R. Schrock and J. A. Osborn,J. Am. Chem. Soc. 98, 2134 (1976).
D. M. Roe and A. G. Massey,J. Organometal. Chem., 28, 273 (1971).
E. W. Abel, M. A. Bennet and G. Wilkinson,J. Chem. Soc. 3178 (1959).
J. Chatt and L. M. Venanzi,J. Chem. Soc. 4735 (1957).
B. J. Fieselmann, D. N. Hendrickson and G. D. Stucky,Inorg. Chem., 17, 2078 (1978).
R. Usón, L. A. Oro and F. Ibañez,Rev. Acad. Ciencias Zaragoza, 31, 169 (1975).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Usón, R., Gimeno, J., Oro, L.A. et al. 2,2′-biimidazole, 2,2′-bibenzimidazole and imidazoles as ligands in cationic rhodium(I) complexes. Transition Met Chem 6, 103–107 (1981). https://doi.org/10.1007/BF00626117
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00626117